meso,meso′-Bis(5-azaindol-2-yl)-Appended meso-meso-Linked Zn(II) Diporphyrin: A Discrete Fluorescent Assembly

被引：17

作者：

Maeda, Chihiro ^{[2
]}

Shinokubo, Hiroshi ^{[1
]}

Osuka, Atsuhiro ^{[2
]}

机构：

[1] Nagoya Univ, Grad Sch Engn, Dept Appl Chem, Chikusa Ku, Nagoya, Aichi 4648603, Japan

[2] Kyoto Univ, Grad Sch Sci, Dept Chem, Sakyo Ku, Kyoto 6068502, Japan

来源：

ORGANIC LETTERS | 2009年 / 11卷 / 22期

关键词：

TEMPLATE-DIRECTED SYNTHESIS; PORPHYRIN ARRAYS; SUPRAMOLECULAR ASSEMBLIES; ELECTRONIC COMMUNICATION; PHOTOSYNTHETIC ANTENNA; MULTIPORPHYRIN ARRAYS; CRYSTAL-STRUCTURE; COORDINATION; OLIGOMERS; INDOLES;

D O I：

10.1021/ol902294r

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Cu(II)-catalyzed intramolecular cyclization of meso-(4-aminopyrid-3-yl)ethynyl Zn(II) porphyrin provided meso-(5-azaindol-2-yl)-substituted Zn(II) porphyrin. meso,meso'-Bis(5-azaindol-2-yl)-substituted diporphyrin 7 was similarly prepared and was found to form a fluorescent trimeric prismatic assembly consisting of single atropisomer 7(in-in).

引用

页码：5322 / 5325

页数：4

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