Formation and Structures of Germanium(II) Aryloxo/Oxo Clusters

被引：14

作者：

Green, Rebecca A. ^{[1
]}

Moore, Curtis ^{[2
]}

Rheingold, Arnold L. ^{[2
]}

Weinert, Charles S. ^{[1
]}

机构：

[1] Oklahoma State Univ, Dept Chem, Stillwater, OK 74078 USA

[2] Univ Calif San Diego, Dept Chem & Biochem, La Jolla, CA 92093 USA

来源：

INORGANIC CHEMISTRY | 2009年 / 48卷 / 16期

关键词：

CRYSTAL-STRUCTURE; COMPLEXES; REACTIVITY; OXYGEN; TIN;

D O I：

10.1021/ic900915q

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of Ge[N(SiMe3)(2)](2) with a phenol lacking a substituent in one ortho position results in the formation of polynuclear clusters having terminal aryloxide ligands and bridging O atoms. Structures of this type have not been observed for germanium(II) aryloxides before, and the source of the bridging O atoms in these clusters was determined to be the phenol reactant.

引用

页码：7510 / 7512

页数：3

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