Resonance Raman spectra of fluoride anion ligated ferryloxo tetramesitylporphyrin pi cation radical compounds

被引：4

作者：

Paeng, KJ

Shin, DH

Paeng, IR

机构：

[1] KOREA BASIC SCI INST,SEOUL 136701,SOUTH KOREA

[2] YONSEI UNIV,DEPT CHEM,WONJU 220701,SOUTH KOREA

[3] SEOUL WOMANS UNIV,DEPT CHEM,SEOUL 139774,SOUTH KOREA

来源：

INORGANIC CHEMISTRY | 1997年 / 36卷 / 13期

关键词：

D O I：

10.1021/ic961094+

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The fluoride anion-ligated ferryloxo tetramesitylporphyrin pi cation radical compound, (TMP.+)(FeO)-O-IV=-(F) (1-F) [v(Fe=O-16) at 807 cm(-1) and v(Fe=O-18) at 771 cm(-1)] was generated by two different routes and structurally characterized by resonance Raman spectroscopy. The green compounds of Hashimoto et al. [v(Fe=O) Eit 828 cm(-1)] and Kincaid et al. [v(Fe=O) at 802 cm(-1)] were reassignd to 1-MeOH and l-Cl, respectively, based on this Raman spectrum and previously reported NMR data.

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页码：2901 / &

页数：4

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