Oxygen Induced Phase Transformation in TC21 Alloy with a Lamellar Microstructure

The main objective of the present study was to understand the oxygen ingress in titanium alloys at high temperatures. Investigations reveal that the oxygen diffusion layer (ODL) caused by oxygen ingress significantly affects the mechanical properties of titanium alloys. In the present study, the high-temperature oxygen ingress behavior of TC21 alloy with a lamellar microstructure was investigated. Microstructural characterizations were analyzed through optical microscopy (OM), scanning electron microscopy (SEM), electron backscatter diffraction (EBSD), and transmission electron microscopy (TEM). Obtained results demonstrate that oxygen-induced phase transformation not only enhances the precipitation of secondary alpha-phase (alpha s) and forms more primary alpha phase (alpha p), but also promotes the recrystallization of the ODL. It was found that as the temperature of oxygen uptake increases, the thickness of the ODL initially increases and then decreases. The maximum depth of the ODL was obtained for the oxygen uptake temperature of 960 degrees C. In addition, a gradient microstructure (alpha p + beta + beta trans)/(alpha p + beta trans)/(alpha p + beta) was observed in the experiment. Meanwhile, it was also found that the hardness and dislocation density in the ODL is higher than that that of the matrix.