Magnetic and crystal structure correlations in PrMn1.5Co0.5Ge2:: a synchrotron diffraction study

被引:3
作者
Ehrenberg, H
Dincer, I
Elmali, A
Elerman, Y
Fuess, H
机构
[1] Tech Univ Darmstadt, Inst Sci Mat, D-64287 Darmstadt, Germany
[2] Ankara Univ, Fac Engn, Dept Engn Phys, TR-06100 Ankara, Turkey
关键词
alloys; light-arc melting; crystal structure and symmetry; magneto-structural coupling; synchrotron radiation;
D O I
10.1016/S0038-1098(02)00478-7
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
Structure details of PrMn2-xCoxGe2, x = 0.5, with the tetragonal ThCr2Si2-type structure have been studied by high-resolution synchrotron powder diffraction. Unit cell parameters a and c, unit cell volume V, c/a, (partial derivativea/partial derivativex)(T) and (partial derivativec/partial derivativex)(T) were determined from Rietveld refinements in the temperature range 10-300 K. The average composition <x> = 0.49(4) is determined based on a detailed diffraction profile analysis. Our measurements indicate three anomalies in the c/a ratio, (partial derivativea/partial derivativex)(T) and (partial derivativec/partial derivativex)(T) at a temperature of about 150 K, which is very close to the transition temperature from antiferromagnetic to ferromagnetic intralayer ordering. (C) 2002 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:429 / 432
页数:4
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