The structure of the peroxo species in the TS-1 catalyst as investigated by resonant Raman spectroscopy

被引：159

作者：

Bordiga, S

Damin, A

Bonino, F

Ricchiardi, G

Lamberti, C

Zecchina, A

机构：

[1] Univ Turin, Dipartimento Chim, IFM, I-10125 Turin, Italy

[2] Univ Turin, INSTM Res Unit, I-10125 Turin, Italy

[3] Univ Turin, INFM UdR, Turin, Italy

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2002年 / 41卷 / 24期

关键词：

D O I：

10.1002/anie.200290032

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The characteristic yellow color of the TS-1/H2O2/H2O system is attributed to a "side-on" Ti-peroxo species, presumed to be the active intermediate in partial oxidation reactions. Resonance Raman spectroscopic analysis of both the zeolite system and a model salt ((NH4+)3 (TiO2F5)3-, see picture) are combined with the analysis of a Ti-free silicalite to prove the structure of the hitherto unknown species.

引用

页码：4734 / 4737

页数：4

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