Application of magnetic Fe3O4 nanoparticles as a reusable heterogeneous catalyst in the synthesis of β-lactams containing amino groups

被引:22
作者
Moslehi, Aleme [1 ]
Zarei, Maaroof [1 ]
机构
[1] Univ Hormozgan, Fac Sci, Dept Chem, Bandar Abbas 71961, Iran
关键词
STEREOSELECTIVE-SYNTHESIS; CHEMOSELECTIVE REDUCTION; BIOLOGICAL EVALUATION; NITRO-COMPOUNDS; 2-AZETIDINONES; HYDROGENATION; NITROARENES; EFFICIENT; DESIGN; IMINES;
D O I
10.1039/c9nj02759a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Herein we report the catalytic activity of magnetic Fe3O4 nanoparticles to promote the reduction of beta-lactams containing nitroaryl groups to beta-lactams containing aminoaryl groups in ethanol. The catalytic experimental conditions have been optimized to maximize the reaction productivity. This convenient and green catalytic methodology is effective to synthesize aminoaryl-beta-lactams containing sustainable groups such as Cl, MeO, alkenyl C?C, pyridine rings and beta-lactam carbonyl.
引用
收藏
页码:12690 / 12697
页数:8
相关论文
共 53 条
[31]   Synthesis, characterization and catalytic activity of Fe3O4@SiO2 nanoparticles supported copper(II) complex as a magnetically recoverable catalyst for the reduction of nitro compounds, Nigrosin and Methylene blue [J].
Nasrollahzadeh, Mahmoud ;
Issaabadi, Zahra ;
Khonakdar, Hossein Ali ;
Wagenknecht, Udo .
SEPARATION AND PURIFICATION TECHNOLOGY, 2018, 203 :185-192
[32]   Recent Developments in the Reduction of Aromatic and Aliphatic Nitro Compounds to Amines [J].
Orlandi, Manuel ;
Brenna, Davide ;
Harms, Reentje ;
Jost, Sonja ;
Benaglia, Maurizio .
ORGANIC PROCESS RESEARCH & DEVELOPMENT, 2018, 22 (04) :430-445
[33]  
Palomo C, 2010, TOP HETEROCYCL CHEM, V22, P211, DOI 10.1007/7081_2009_11
[34]  
Patel RB, 2006, INDIAN J CHEM B, V45, P773
[35]   Chemical Synthesis of β-Lactams: Asymmetric Catalysis and Other Recent Advances [J].
Pitts, Cody Ross ;
Lectka, Thomas .
CHEMICAL REVIEWS, 2014, 114 (16) :7930-7953
[36]  
Plietker B., 2008, IRON CATALYSIS ORGAN
[37]   Magnetically Recoverable Nanocatalysts [J].
Polshettiwar, Vivek ;
Luque, Rafael ;
Fihri, Aziz ;
Zhu, Haibo ;
Bouhrara, Mohamed ;
Bassett, Jean-Marie .
CHEMICAL REVIEWS, 2011, 111 (05) :3036-3075
[38]   Synthesis of some novel indeno[1,2-b]quinoxalin spiro-β-lactam conjugates [J].
Rad, Javad Ameri ;
Jarrahpour, Aliasghar ;
Ersanli, Cem Cuneyt ;
Atioglu, Zeliha ;
Akkurt, Mehmet ;
Turos, Edward .
TETRAHEDRON, 2017, 73 (08) :1135-1142
[39]   One Pot, Simple, and Efficient Synthesis of 2-Azetidinones Mediated by 3-(Diethoxyphosphoryloxy)-1,2,3-benzotriazin-4-(3H)-one [J].
Saraei, Mahnaz ;
Zarei, Maaroof ;
Zavar, Saleheh .
LETTERS IN ORGANIC CHEMISTRY, 2017, 14 (08) :597-602
[40]   Chemoselective reduction of a nitro group through transfer hydrogenation catalysed by Ru0-nanoparticles stabilized on modified Montmorillonite clay [J].
Sarmah, Podma Pollov ;
Dutta, Dipak Kumar .
GREEN CHEMISTRY, 2012, 14 (04) :1086-1093