Functionalised azetidines as ligands: some basic coordination chemistry

被引：7

作者：

Lee, Young Hoon ^{[1
]}

Kim, Hyang Hoo ^{[1
]}

Thuery, Pierre ^{[2
]}

Harrowfield, Jack M. ^{[3
]}

Lim, Woo Taik ^{[4
]}

Kim, Bok Jo ^{[5
]}

Kim, Yang ^{[1
]}

机构：

[1] Kosin Univ, Dept Chem & Adv Mat, Pusan 606701, South Korea

[2] CEA, CNRS, URA 331, IRAMIS,LCCEf,SIS2 M, F-91191 Gif Sur Yvette, France

[3] Univ Strasbourg, Inst Sci & Ingn Supramol, F-67083 Strasbourg, France

[4] Andong Natl Univ, Dept Appl Chem, Andong, Kyungpook, South Korea

[5] Kyungwoon Univ, Dept Biomed Lab Sci, Gumi Si 730739, Kyungpook, South Korea

来源：

JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY | 2009年 / 65卷 / 1-2期

关键词：

Azetidines; Metal complexes; Crystal structures; Lattice interactions; COUPLING REACTIONS; COMPLEXES;

D O I：

10.1007/s10847-009-9635-5

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Crystal structure determinations on Cu(II) and Zn(II) complexes of tridentate and quadridentate azetidine derivatives show the ligands to be facultative for square-pyramidal and trigonal bipyramidal coordination geometries. While various contributions to the chirality of the complexes are possible, single diastereoisomeric forms (as enantiomer mixtures) have been isolated in all cases in the solid state. Analysis of lattice interactions indicates that H-bonding and aromatic stacking interactions are generally important.

引用

页码：65 / 71

页数：7

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