Isopropylation of naphthalene over mesostructured aluminosilicate nanoparticles with wormhole framework structures

被引:0
|
作者
Zhai, Shang-Ru [1 ]
Ha, Chang-Sik [2 ]
Liu, Yong [3 ]
Qiu, Hua-Yu [3 ]
Wu, Dong [4 ]
Sun, Yu-Han [4 ]
Wang, Shao-Jun [1 ]
Zhai, Bin [1 ]
机构
[1] Dalian Inst Light Ind, Dept Chem Engn & Mat, Dalian 116034, Peoples R China
[2] Pusan Natl Univ, Dept Polymer Sci & Engn, Natl Res Lab Nanoinformat Mat, Busan 609735, South Korea
[3] Hangzhou Teachers Coll, Key Lab Organosilicon Chem & Mat Technol, Educ Minist, Hangzhou 310012, Zhejiang, Peoples R China
[4] Chinese Acad Sci, Inst Coal Chem, State Key Lab Coal Convers, Taiyuan 030001, Peoples R China
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中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
The preparation and catalytic properties in isopropylation of naphthalene of nanosized mesostructured alumiosilicate with worm-like framework structures were presented in this work. Catalytic results showed that, under optmium conditions, the present nanocatalyst exhibited high activity making ca. 90 mol% of naphthalene conversion into mono- ,di- and triisopropyl substituted derivatives. It should be mentioned that, however, the present nanocatalyst showed no considerable selectivity to objective products, and this may be attributed to its somewhat large mesopores in comparsion with microporous alkylating catalysts.
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页码:807 / 810
页数:4
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