Modelling of Pb-(TAPS)x-(OH)y system and refinement of stability constants in the region of lead hydrolysis and lead hydroxide precipitation

The influence of [(2-hydroxy-1,1-bis(hydroxymethyl)ethyl)amino]-l-propanesulfonic acid (TAPS) on solutions containing lead(II) was studied by direct current polarography (DCP) and glass electrode potentiometry (GEP). The readings were taken at fixed total TAPS to total lead(II) concentration ratios and various pH values, at 25.0 +/- 0.1 degrees C and ionic strength 0.1 M KNO3. Due to the basic pK(a) of the ligand, which occurs in the pH range where large amount of lead polynuclear species are formed, and the occurrence of ligand adsorption, that disabled the use of high concentrations of TAPS on DCP experiments, GEP and DCP experimental conditions were put to the limit in order to provide the correct Pb-TAPS-OH model and reliable stability constants. The proposed final model is: PbL, PbL2, PbL2(OH) and PbL2(OH)(2) with overall stability constants values, as log beta, 3.27 +/- 0.06, 6.5 +/- 0.1, 12.7 +/- 0.1 and 17.27 +/- 0.06, respectively. A comparative analysis of the strength of complexation of TAPS and a structural related buffer, 2-hydroxy-3-[tris(hydroxymethyl)methylamino]1 -propanesulfonic acid (TAPSO), with lead is also discussed. (c) 2006 Elsevier B.V. All rights reserved.