Composition and Shape Control in the Construction of Functional Nickel Hexacyanoferrate Nanointerfaces

被引：26
作者：
Chen, Wei [1 ]
Tang, Jian [1 ]
Xia, Xing-Hua [1 ]
机构：
[1] Nanjing Univ, Key Lab Analyt Chem Life Sci, Sch Chem & Chem Engn, Nanjing 210093, Peoples R China
来源：
JOURNAL OF PHYSICAL CHEMISTRY C | 2009年 / 113卷 / 52期
基金：
中国国家自然科学基金;
关键词：
SWITCHED ION-EXCHANGE; PRUSSIAN-BLUE; PLATINUM NANOPARTICLES; NANOCRYSTALS; FERROMAGNETISM; SURFACES; CYANIDE; FACETS;
D O I：
10.1021/jp908112u
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The composition/structure-function relationship is the underlying motive for discovering and designing novel nanomaterials with distinct properties and for special applications. In this paper, we for the first time investigated the structure and composition related properties of inorganic coordination complexes of nickel hexacyanoferrate. The formation mechanism of nickel hexacyanoferrate with different compositions is proposed by investigating the role of different reactants. Base on this mechanism, it is now well established that potential controlling technique can be employed to synthesize composition and morphology controlled nickel hexacyanoferrate functional nanointerfaces with specific properties. The composition/structure-function relationship of these nanointerfaces is illustrated. As a demonstration, sole compositional nickel hexacyanoferrate concave nanocubes are synthesized and used as functional nanointerface for electrically switched ion exchange and cesium ion sensing.
引用
收藏
页码：21577 / 21581
页数：5
相关论文
共 26 条
  • [1] POLYNUCLEAR NICKEL HEXACYANOFERRATES - MONITORING OF FILM GROWTH AND HYDRATED COUNTER-CATION FLUX STORAGE DURING REDOX REACTIONS
    BACSKAI, J
    MARTINUSZ, K
    CZIROK, E
    INZELT, G
    KULESZA, PJ
    MALIK, MA
    [J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1995, 385 (02) : 241 - 248
  • [2] Nickel hexacyanoferrate multilayers on functionalized mesoporous silica supports for selective sorption and sensing of cesium
    Chang, Chin-Yuan
    Chau, Lai-Kwan
    Hu, Wei-Ping
    Wang, Chiou-Yann
    Liao, Ju-Hsiou
    [J]. MICROPOROUS AND MESOPOROUS MATERIALS, 2008, 109 (1-3) : 505 - 512
  • [3] Highly stable nickel hexacyanoferrate nanotubes for electrically switched ion exchange
    Chen, Wei
    Xia, Xing-Hua
    [J]. ADVANCED FUNCTIONAL MATERIALS, 2007, 17 (15) : 2943 - 2948
  • [4] Metal hexacyanoferrates: Electrosynthesis, in situ characterization, and applications
    de Tacconi, NR
    Rajeshwar, K
    Lezna, RO
    [J]. CHEMISTRY OF MATERIALS, 2003, 15 (16) : 3046 - 3062
  • [5] The new face of catalysis
    Feldheim, Daniel L.
    [J]. SCIENCE, 2007, 316 (5825) : 699 - 700
  • [6] Electromechanical phase transition in hexacyanometallate nanostructure (Prussian blue)
    Gimenez-Romero, David
    Agrisuelas, Jeronimo
    Garcia-Jareno, Jose Juan
    Gregori, Joan
    Gabrielli, Claude
    Perrot, Hubert
    Vicente, Francisco
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (22) : 7121 - 7126
  • [7] Tuning intercalation sites in nickel hexacyanoferrate using lattice nonstoichiometry
    Hao, XG
    Schwartz, DT
    [J]. CHEMISTRY OF MATERIALS, 2005, 17 (23) : 5831 - 5836
  • [8] The synergistic effect of Prussian-Blue-grafted carbon nanotube/poly(4-vinylpyridine) composites for amperometric sensing
    Li, Jian
    Qiu, Jian-Ding
    Xu, Jing-Juan
    Chen, Hong-Yuan
    Xia, Xing-Hua
    [J]. ADVANCED FUNCTIONAL MATERIALS, 2007, 17 (09) : 1574 - 1580
  • [9] Metal ion separations using electrically switched ion exchange
    Lilga, MA
    Orth, RJ
    Sukamto, JPH
    Haight, SM
    Schwartz, DT
    [J]. SEPARATION AND PURIFICATION TECHNOLOGY, 1997, 11 (03) : 147 - 158
  • [10] Novel hybrid materials with high stability for electrically switched ion exchange: carbon nanotube-polyaniline-nickel hexacyanoferrate nanocomposites
    Lin, YH
    Cui, XL
    [J]. CHEMICAL COMMUNICATIONS, 2005, (17) : 2226 - 2228
123