A historical perspective on porphyrin-based metal-organic frameworks and their applications

被引：225

作者：

Zhang, Xuan ^{[1
,2
]}

Wasson, Megan C. ^{[1
,2
]}

Shayan, Mohsen ^{[5
]}

Berdichevsky, Ellan K. ^{[5
]}

Ricardo-Noordberg, Joseph ^{[6
,7
]}

Singh, Zujhar ^{[6
,7
]}

Papazyan, Edgar K. ^{[8
]}

Castro, Anthony J. ^{[8
]}

Marino, Paola ^{[6
,7
]}

Ajoyan, Zvart ^{[6
,7
]}

Chen, Zhijie ^{[1
,2
]}

Islamoglu, Timur ^{[1
,2
]}

Howarth, Ashlee J. ^{[6
,7
]}

Liu, Yangyang ^{[8
]}

Majewski, Marek B. ^{[6
,7
]}

Katz, Michael J. ^{[5
]}

Mondloch, Joseph E. ^{[4
]}

Farha, Omar K. ^{[1
,2
,3
]}

机构：

[1] Northwestern Univ, Dept Chem, Evanston, IL 60208 USA

[2] Northwestern Univ, Int Inst Nanotechnol, Evanston, IL 60208 USA

[3] Northwestern Univ, Dept Chem & Biol Engn, 2145 Sheridan Rd, Evanston, IL 60208 USA

[4] Univ Wisconsin Stevens Point, Dept Chem, 2100 Main St, Stevens Point, WI 54481 USA

[5] Mem Univ Newfoundland, Dept Chem, 230 Elizabeth Ave, St John, NF A1C 5S7, Canada

[6] Concordia Univ, Dept Chem & Biochem, 7141 Sherbrooke St W, Montreal, PQ H4B 1R6, Canada

[7] Concordia Univ, Ctr NanoSci Res, 7141 Sherbrooke St W, Montreal, PQ H4B 1R6, Canada

[8] Calif State Univ Los Angeles, Dept Chem & Biochem, 5151 State Univ Dr, Los Angeles, CA 90032 USA

来源：

COORDINATION CHEMISTRY REVIEWS | 2021年 / 429卷

基金：

加拿大自然科学与工程研究理事会;

关键词：

Porphyrin; Metal-organic frameworks; Catalysis; Sensing; Biomedical applications; PHOTOCATALYTIC HYDROGEN EVOLUTION; EFFECTIVE PHOTODYNAMIC THERAPY; VISIBLE-LIGHT PHOTOREDUCTION; FUNCTIONALIZED ZIRCONIUM MOF; MUSTARD-GAS SIMULANT; HIGHLY EFFICIENT; OXYGEN REDUCTION; METALLOPORPHYRIN FRAMEWORK; THIN-FILMS; ELECTROCHEMICAL REDUCTION;

D O I：

10.1016/j.ccr.2020.213615

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Porphyrins are important molecules widely found in nature in the form of enzyme active sites and visible light absorption units. Recent interest in using these functional molecules as building blocks for the construction of metal-organic frameworks (MOFs) have rapidly increased due to the ease in which the locations of, and the distances between, the porphyrin units can be controlled in these porous crystalline materials. Porphyrin-based MOFs with atomically precise structures provide an ideal platform for the investigation of their structure-function relationships in the solid state without compromising accessibility to the inherent properties of the porphyrin building blocks. This review will provide a historical overview of the development and applications of porphyrin-based MOFs from early studies focused on design and structures, to recent efforts on their utilization in biomimetic catalysis, photocatalysis, electrocatalysis, sensing, and biomedical applications. (C) 2020 Elsevier B.V. All rights reserved.

引用

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