On the Prins reaction of terminal olefins and formaldehyde in trifluoroacetic acid

被引：4

作者：

Almohseni, Hasanain A. A. ^{[1
]}

Stent, Matthew A. H. ^{[1
]}

Hodgson, David M. ^{[1
]}

机构：

[1] Univ Oxford, Dept Chem, Chem Res Lab, Mansfield Rd, Oxford OX1 3TA, England

来源：

CHEMISTRY OF HETEROCYCLIC COMPOUNDS | 2018年 / 54卷 / 04期

基金：

英国工程与自然科学研究理事会;

关键词：

formaldehyde; terminal alkenes; tetrahydropyrans; trifluoroacetic acid; Prins reaction; ALPHA-OLEFINS; HYDROGEN HALIDES; CONDENSATION; CYCLIZATION;

D O I：

10.1007/s10593-018-2293-z

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The Prins reaction of 1-heptene, as a representative terminal alkene, with formaldehyde in trifluoroacetic acid produces 3-butyl-4-(trifluoroacetoxy)tetrahydropyran and/or 3-butyl-4-hydroxytetrahydropyran; it does not provide (as previously reported by Talipov and coworkers) a route to 3-alkyl-2,5-dihydrofurans and 4-alkyl-3-hydroxytetrahydrofurans.

引用

页码：474 / 477

页数：4

共 26 条

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