Near infrared two photon imaging using a bright cationic Yb(III) bioprobe spontaneously internalized into live cells

被引：57

作者：

Anh Thy Bui ^{[1
]}

Beyler, Maryline ^{[2
]}

Grichine, Alexei ^{[3
]}

Duperray, Alain ^{[3
]}

Mulatier, Jean-Christophe ^{[1
]}

Guyot, Yannick ^{[4
,5
]}

Andraud, Chantal ^{[1
]}

Tripier, Raphael ^{[2
]}

Brasselet, Sophie ^{[6
]}

Maury, Olivier ^{[1
]}

机构：

[1] Univ Claude Bernard Lyon 1, Ecole Normale Super Lyon, CNRS, UMR 5182,Lab Chim, 46 Allee Italie, F-69364 Lyon, France

[2] Univ Brest, UMR CNRS 6521, UFR Sci & Tech, 6 Ave Victor le Gorgeu,CS 93837, F-29238 Brest 3, France

[3] Univ Claude Bernard Lyon 1, Inst Lumiere Matiere, UMR 5306, CNRS, 10 Rue Ada Byron, F-69622 Villeurbanne, France

[4] INSERM, U1209, F-38000 Grenoble, France

[5] Univ Grenoble Alpes, IAB, F-38000 Grenoble, France

[6] Univ Aix Marseille, CNRS, Cent Marseille, Inst Fresnel, F-13013 Marseille, France

来源：

CHEMICAL COMMUNICATIONS | 2017年 / 53卷 / 44期

关键词：

FLUORESCENT-PROBES; LANTHANIDE BIOPROBES; EFFICIENT SENSITIZATION; EUROPIUM COMPLEXES; RADIATIVE LIFETIME; EXCITED-STATES; QUANTUM YIELDS; MICROSCOPY; LUMINESCENCE; YTTERBIUM;

D O I：

10.1039/c7cc02835k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An Yb(III) complex based on a dimethyl cyclen macrocyclic ligand functionalized by charge transfer antennae was prepared. This cationic [YbL3](+) complex is stable and soluble in water and presents interesting photophysical nonlinear properties. It is spontaneously internalized and accumulates in live cells. High quality images have been obtained both in a classical NIR-to-vis configuration and in the more challenging NIR-to-NIR one.

引用

页码：6005 / 6008

页数：4

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