Stereochemistry and mechanism of oxidative 1,4-addition of trifluoroacetamide to 2,3-dimethylbuta-1,3-diene

被引：9

作者：

Astakhova, Vera V. ^{[1
]}

Moskalik, Mikhail Yu. ^{[1
]}

Sterkhova, Irina V. ^{[1
]}

Shainyan, Bagrat A. ^{[1
]}

机构：

[1] Russian Acad Sci, Siberian Branch, AE Favorsky Irkutsk Inst Chem, Irkutsk 664033, Russia

来源：

MENDELEEV COMMUNICATIONS | 2017年 / 27卷 / 03期

基金：

俄罗斯基础研究基金会;

关键词：

CATALYTIC ASYMMETRIC AMINOHYDROXYLATION; CYCLIC DIENES; T-BUOI; OLEFINS; 1,4-DIAMINATION; AZIRIDINATION; CYCLOADDITION; FRAMEWORK; AMIDES;

D O I：

10.1016/j.mencom.2017.05.026

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Oxidative addition of trifluoroacetamide to 2,3-dimethylbuta-1,3-diene leads to N,N'-[(2E)-2,3-dimethylbut-2-ene-1,4-diyl]bis(trifluoroacetamide) and [(2RS,3SR)-N-(2,3-dihydroxy-4-iodo-2,3-dimethylbutyl)trifluoroacetamide. A tentative mechanism is proposed.

引用

页码：293 / 295

页数：3

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