lead-acid cell;
fast charge;
electrode kinetics;
mathematical modeling;
D O I:
10.1016/S0378-7753(00)00381-5
中图分类号:
O64 [物理化学(理论化学)、化学物理学];
学科分类号:
070304 ;
081704 ;
摘要:
Cell behavior is numerically investigated for fast charging of a lead-acid cell under constant current or pulsed current. A model used in the simulation has been developed to predict the cell performance by considering the solid-state reaction at the negative electrode. By incorporating a rest period and a depolarization pulse on high rate charge, it is possible to avoid deterioration of the cell performance due to an increase in internal resistance. Thus, fast charging of a lead-acid cell can be achieved without a loss of cycle-life, despite the fact that higher currents are forced into the cell. (C) 2000 Elsevier Science S.A. All rights reserved.