Syntheses, structures, and photoluminescence of 1-D lanthanide coordination polymers

被引：47
作者：
Yang, Xiaoping [1 ]
Jones, Richard A. [1 ]
Rivers, Joseph H. [1 ]
Wong, Wai-Kwok [2 ,3 ]
机构：
[1] Univ Texas Austin, Dept Chem & Biochem, Austin, TX 78712 USA
[2] Hong Kong Baptist Univ, Dept Chem, Kowloon Tong, Hong Kong, Peoples R China
[3] Hong Kong Baptist Univ, Ctr Adv Luminescence Mat, Kowloon Tong, Hong Kong, Peoples R China
来源：
DALTON TRANSACTIONS | 2009年 / 47期
关键词：
METAL-ORGANIC FRAMEWORKS; BUILDING UNITS; COMPLEXES; LIGANDS; LUMINESCENCE; NETWORKS; DESIGN; COUNTERANIONS; ENCAPSULATION; ARCHITECTURE;
D O I：
10.1039/b910588c
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Five new lanthanide 1-D coordination polymers are reported which are formed from flexible salen type Schiff-base ligands H2L and H2L' (H2L = N, N-1-ethylene bis(salicylideneimine); H2L' = N,N-1-bis(3-methoxysalicylidene) ethylene-1,2-diamine). The polymeric structures are formed by bridging neutral H2L units in the case of {[Ln(2)L(2)(CF3SO3)(H2L)(4)(MeOH)]center dot CF3SO3}(n) (Ln = Eu (1), Nd (2) and Er (3)), and by acetate (OAc-) groups in [Yb-2(L)(2)(OAc)(2)(MeOH)(2)](n) (4) and {[Tb-3(L')(2)(OAc)(5)]center dot Et2O center dot(MeOH)(0.5)}(n) (5). The structures of 1-5 were determined by single crystal X-ray crystallographic studies and the luminescence properties of 1 and 5 in MeOH solution were determined.
引用
收藏
页码：10505 / 10510
页数：6
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