Efficient Fluoride Removal and Dye Degradation of Contaminated Water Using Fe/Al/Ti Oxide Nanocomposite

被引:42
作者
Mukherjee, Arnab [1 ]
Adak, Mrinal K. [1 ]
Upadhyay, Sudipta [1 ]
Khatun, Julekha [1 ]
Dhak, Prasanta [2 ]
Khawas, Sadhana [1 ]
Ghorai, Uttam Kumar [3 ]
Dhak, Debasis [1 ]
机构
[1] Sidho Kanho Birsha Univ, Dept Chem, Nanomat Res Lab, Purulia 723104, India
[2] Techno India Univ, Dept Chem, Kolkata 700091, India
[3] Ramakrishna Mission Vidyamandira, Dept Ind Chem, Belur Math 711202, Howrah, India
关键词
METHYLENE-BLUE DYE; PHOTOCATALYTIC DEGRADATION; AQUEOUS-SOLUTION; DRINKING-WATER; TREATMENT TECHNOLOGIES; NANO-ADSORBENT; TEXTILE DYE; ADSORPTION; NANOPARTICLES; PHOTODEGRADATION;
D O I
10.1021/acsomega.9b00252
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The trimetallic Fe/Al/Ti (1:1:1) nanocomposite (FAT), synthesized by an adaptable tuned chemical route, offers a new approach for water treatment, for example, the de-fluoridation and photodegradation soluble dye methylene blue (MB) at pH 7. FAT acted as a good fluoride scavenger in the presence of other co-ions and within a widespread pH range (pH 2-11). The photodegradation efficiencies were >90% for different concentrations of MB solutions. The characterization of FAT includes thermogravimetric analysis, X-ray diffraction, Fourier transform-infrared spectroscopy, scanning electron microscopy, transmission electron microscopy, and zeta-potential analysis. Furthermore, the regeneration efficiencies of both the water treatments were checked, where the removal efficiency was not hampered significantly even after five batches. Spectroscopic techniques were adopted to perform the kinetic studies and to propose the probable mechanistic paths.
引用
收藏
页码:9686 / 9696
页数:11
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