TiC whisker reinforced ultra-fine TiC-based cermets: Microstructure and mechanical properties

被引:51
作者
Xiong, Huiwen [1 ]
Li, Zhiyou [1 ]
Zhou, Kechao [1 ]
机构
[1] Cent S Univ, State Key Lab Powder Met, Changsha 410083, Peoples R China
关键词
Hardness; TiC; Cermets; Whisker reinforced; Toughness; WC-CO; CARBOTHERMAL REDUCTION; POWDER SIZE; TI(C; NONSTOICHIOMETRY; TOUGHNESS; CARBIDES; HARDNESS;
D O I
10.1016/j.ceramint.2016.01.069
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
TiC whisker reinforced ultra-fine TiC-based cermets were fabricated and their microstructures as well as mechanical properties were characterized and compared with microsized and ultra-fine cermets. The effects of high energy milling and subsequent annealing on the composition and microstructure of microsized TiC powders were studied. It was shown that the particle size distribution of TiC powders played a critical role in determining cermets' microstructure and properties. Inverse grain (White core with grey rim) only exists in ultra-fine cermet with a narrow size distribution of annealed TiC powders. Large discrepancy of larger TiC powders (microsized particles or whiskers) and ultra-fine particles in size resulted in a bimodal grain size feature. Additionally, mechanical property testing was conducted and was related to the microstructural features. The whisker reinforced cermets own much higher toughness of 12.43 Mpa m(1/2) than the microsized and ultra-fine cermets, with a hardness (Hv(30), 1620) between them. (c) 2016 Elsevier Ltd and Techna Group S.r.l. All rights reserved.
引用
收藏
页码:6858 / 6867
页数:10
相关论文
共 32 条
  • [1] Microstructure and mechanical properties of ultrafine Ti(CN)-based cermets fabricated from nano/submicron starting powders
    Chao, S
    Liu, N
    Yuan, YP
    Han, CL
    Xu, YD
    Shi, M
    Feng, JP
    [J]. CERAMICS INTERNATIONAL, 2005, 31 (06) : 851 - 862
  • [2] Inverse core-rim microstructure in (Ti,Ta)(C,N)-based cermets developed by a mechanically induced self-sustaining reaction
    Chicardi, E.
    Cordoba, J. M.
    Sayagues, M. J.
    Gotor, F. J.
    [J]. INTERNATIONAL JOURNAL OF REFRACTORY METALS & HARD MATERIALS, 2012, 31 : 39 - 46
  • [3] Effect of submicron Ti(C,N) on the microstructure and the mechanical properties of Ti(C,N)-based cermets
    Demoly, A.
    Lengauer, W.
    Veitsch, C.
    Rabitsch, K.
    [J]. INTERNATIONAL JOURNAL OF REFRACTORY METALS & HARD MATERIALS, 2011, 29 (06) : 716 - 723
  • [4] Microstructure and cutting performance investigation of Ti(C, N)-based cermets containing various types of secondary carbides
    Dizaji, V. Rahimi
    Rahmani, M.
    Sani, M. Faghihi
    Nemati, Z.
    Akbari, J.
    [J]. INTERNATIONAL JOURNAL OF MACHINE TOOLS & MANUFACTURE, 2007, 47 (05) : 768 - 772
  • [5] Synthesis, sintering, and mechanical properties of nanocrystalline cemented tungsten carbide - A review
    Fang, Z. Zak
    Wang, Xu
    Ryu, Taegong
    Hwang, Kyu Sup
    Sohn, H. Y.
    [J]. INTERNATIONAL JOURNAL OF REFRACTORY METALS & HARD MATERIALS, 2009, 27 (02) : 288 - 299
  • [6] Correlation of transverse rupture strength of WC-Co with hardness
    Fang, ZZ
    [J]. INTERNATIONAL JOURNAL OF REFRACTORY METALS & HARD MATERIALS, 2005, 23 (02) : 119 - 127
  • [7] Effects of ball milling time on the synthesis and consolidation of nanostructured WC-Co composites
    Hewitt, Stephen A.
    Kibble, Kevin A.
    [J]. INTERNATIONAL JOURNAL OF REFRACTORY METALS & HARD MATERIALS, 2009, 27 (06) : 937 - 948
  • [8] Microstructure, hardness and toughness of nanostructured and conventional WC-Co composites
    Jia, K
    Fischer, TE
    Gallois, B
    [J]. NANOSTRUCTURED MATERIALS, 1998, 10 (05): : 875 - 891
  • [9] Study on phase evolution during reaction synthesis of ultrafine (Ti, W, Mo, V)(CN)-Ni composite powders
    Jin, Yongzhong
    Li, Ying
    Wang, Yankun
    Ye, Jinwen
    [J]. MATERIALS CHEMISTRY AND PHYSICS, 2009, 118 (01) : 191 - 196
  • [10] Effect of nano-size powders on the microstructure of Ti(C,N)-xWC-Ni cermets
    Jung, Jinkwan
    Kang, Shinhoo
    [J]. JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2007, 90 (07) : 2178 - 2183