Non-isothermal modelling of the all-vanadium redox flow battery

被引：239
作者：
Al-Fetlawi, H. [1 ]
Shah, A. A. [1 ]
Walsh, F. C. [1 ]
机构：
[1] Univ Southampton, Energy Technol Res Group, Sch Engn Sci, Southampton SO17 1BJ, Hants, England
来源：
ELECTROCHIMICA ACTA | 2009年 / 55卷 / 01期
关键词：
Vanadium; Modelling and simulation; Energy balance; Temperature; ION-EXCHANGE MEMBRANES; MATHEMATICAL-MODEL; FUEL-CELLS; SIMULATION; WATER; PERFORMANCE; DEGRADATION; DIFFUSION;
D O I：
10.1016/j.electacta.2009.08.009
中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
An non-isothermal model for the all-vanadium redox flow battery (RFB) is presented. The two-dimensional model is based on a comprehensive description of mass. charge, energy and momentum transport and conservation, and is combined with a global kinetic model for reactions involving vanadium species. Heat is generated as a result of activation losses, electrochemical reaction and ohmic resistance. Numerical simulations demonstrate the effects of changes in the operating temperature on performance. It is shown that variations in the electrolyte flow rate and the magnitude of the applied current substantially alter the charge/discharge characteristics, the temperature rise and the distribution of temperature. The influence of heat losses on the charge/discharge behaviour and temperature distribution is investigated. Conditions for localised heating and membrane degradation are discussed. (C) 2009 Elsevier Ltd. All rights reserved.
引用
收藏
页码：78 / 89
页数：12
相关论文
共 50 条
[11]   Effect of flow field on the performance of an all-vanadium redox flow battery [J].
Kumar, S. ;
Jayanti, S. .
JOURNAL OF POWER SOURCES, 2016, 307 :782-787
[12]   Analysis of Concentration Overpotential in an All-Vanadium Redox Flow Battery [J].
Murthy, Sri Krishna ;
Sharma, Ashwini Kumar ;
Choo, Clement ;
Birgersson, Erik .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2018, 165 (09) :A1746-A1752
[13]   Modeling of an All-Vanadium Redox Flow Battery and Optimization of Flow Rates [J].
Xiong Binyu ;
Zhao Jiyun ;
Li Jinbin .
2013 IEEE POWER AND ENERGY SOCIETY GENERAL MEETING (PES), 2013,
[14]   Application of the commercial ion exchange membranes in the all-vanadium redox flow battery [J].
Hwang, Gab-Jin ;
Kim, Sang-Won ;
In, Dae-Min ;
Lee, Dae-Yeop ;
Ryu, Cheol-Hwi .
JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY, 2018, 60 :360-365
[15]   Characteristics of the all-vanadium redox flow battery using ammonium metavanadate electrolyte [J].
Jung, Bo-Young ;
Ryu, Cheol-Hwi ;
Hwang, Gab-Jin .
KOREAN JOURNAL OF CHEMICAL ENGINEERING, 2022, 39 (09) :2361-2367
[16]   Efficiency improvement of an all-vanadium redox flow battery by harvesting low-grade heat [J].
Reynard, Danick ;
Dennison, C. R. ;
Battistel, Alberto ;
Girault, Hubert H. .
JOURNAL OF POWER SOURCES, 2018, 390 :30-37
[17]   Research progress in preparation of electrolyte for all-vanadium redox flow battery [J].
Guo, Yun ;
Huang, Jie ;
Feng, Jun-Kai .
JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY, 2023, 118 :33-43
[18]   Verified reduction of dimensionality for an all-vanadium redox flow battery model [J].
Sharma, A. K. ;
Ling, C. Y. ;
Birgersson, E. ;
Vynnycky, M. ;
Han, M. .
JOURNAL OF POWER SOURCES, 2015, 279 :345-350
[19]   Model of charge/discharge operation for all-vanadium redox flow battery [J].
Li, Minghua ;
Fan, Yongsheng ;
Wang, Baoguo .
Huagong Xuebao/CIESC Journal, 2014, 65 (01) :313-318
[20]   Thermal modeling and temperature control of an all-vanadium redox flow battery [J].
Shen, HaiFeng ;
Zhu, XinJian ;
Cao, Hongfei ;
Xue, Binqiang .
2019 12TH ASIAN CONTROL CONFERENCE (ASCC), 2019, :432-437
12345