Robust Heterometallic CoIILa2III-Organic Framework for the Highly Efficient Separation of Acetylene from Light Hydrocarbon Mixtures

被引：25

作者：

Chen, Hongtai ^{[1
]}

Feng, Lei ^{[2
]}

Zhang, Xiutang ^{[1
]}

Gao, Zhi-Yong ^{[3
,4
]}

Sun, Di ^{[2
,5
,6
]}

机构：

[1] North Univ China, Coll Sci, Dept Chem, Taiyuan 030051, Peoples R China

[2] Shandong Univ, Sch Chem & Chem Engn, State Key Lab Crystal Mat, Jinan 250100, Peoples R China

[3] Henan Normal Univ, Collaborat Innovat Ctr Henan Prov Green Mfg Fine, Sch Chem & Chem Engn, Xinxiang 453007, Henan, Peoples R China

[4] Henan Normal Univ, Key Lab Green Chem Media & React, Minist Educ, Xinxiang 453007, Henan, Peoples R China

[5] Liaocheng Univ, Shandong Prov Key Lab Chem Energy Storage & Novel, Liaocheng 252000, Shandong, Peoples R China

[6] Liaocheng Univ, Sch Chem & Chem Engn, Liaocheng 252000, Shandong, Peoples R China

来源：

INORGANIC CHEMISTRY | 2021年 / 60卷 / 05期

关键词：

Breakthrough experiment - Carboxyl groups - Heterometallics - Ideal adsorbed solution theory - Industrial conditions - Inner surfaces - Light hydrocarbon - Window Size;

D O I：

10.1021/acs.inorgchem.0c03537

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A highly robust heterometallic (CoLa2III)-La-II-organic framework (NUC-19) is synthesized and features 1D rectangle-like channels with a window size of 3.4 X 6.3 angstrom(2) and a carboxyl-group-modified inner surface. NUC-19 exhibits significantly differential uptake for C2H2, C2H4, and CH4, and the ideal adsorbed solution theory selectivities of C2H2/C2H4 (1:99, v/v) and C2H2/CH4 (50:50, v/v) at room temperature can reach up to 4.0 and 79.7, respectively. Fixed-bed dynamic breakthrough experiments under simulated industrial conditions indicate that NUC-19 could efficiently trap C2H2 from mixed gases of C2H2/CH4 and C2H2/C2H4.

引用

页码：2878 / 2882

页数：5

共 57 条

[1] Fine Tuning and Specific Binding Sites with a Porous Hydrogen-Bonded Metal-Complex Framework for Gas Selective Separations [J].

Bao, Zongbi ;

Xie, Danyan ;

Chang, Ganggang ;

Wu, Hui ;

Li, Liangying ;

Zhou, Wei ;

Wang, Hailong ;

Zhang, Zhiguo ;

Xing, Huabin ;

Yang, Qiwei ;

Zaworotko, Michael J. ;

Ren, Qilong ;

Chen, Banglin .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2018, 140 (13) :4596-4603

[2] Potential of polarizable force fields for predicting the separation performance of small hydrocarbons in M-MOF-74 [J].

Becker, Tim M. ;

Luna-Triguero, Azahara ;

Manuel Vicent-Luna, Jose ;

Lin, Li-Chiang ;

Dubbeldam, David ;

Calero, Sofia ;

Vlugt, Thijs J. H. .

PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2018, 20 (45) :28848-28859

[3] Selective adsorption of C2H2 and CO2 from CH4 in an isoreticular series of MOFs constructed from unsymmetrical diisophthalate linkers and the effect of alkoxy group functionalization on gas adsorption [J].

Chen, Fengli ;

Wang, Yao ;

Bai, Dongjie ;

He, Minghui ;

Gao, Xiaoxia ;

He, Yabing .

JOURNAL OF MATERIALS CHEMISTRY A, 2018, 6 (08) :3471-3478

[4] One Robust Microporous TmIII-Organic Framework for Highly Catalytic Activity on Chemical CO2 Fixation and Knoevenagel Condensation [J].

Chen, Hongtai ;

Hu, Tuoping ;

Fan, Liming ;

Zhang, Xiutang .

INORGANIC CHEMISTRY, 2021, 60 (02) :1029-1037

[5] Nanocage-Based In III{TbIII}2-Organic Framework Featuring Lotus-Shaped Channels for Highly Efficient CO2 Fixation and I2 Capture [J].

Chen, Hongtai ;

Fan, Liming ;

Zhang, Xiutang ;

Ma, Lufang .

ACS APPLIED MATERIALS & INTERFACES, 2020, 12 (24) :27803-27811

[6] A highly robust heterometallic TbIII/NiII-organic framework for C2 hydrocarbon separation and capture [J].

Chen, Hongtai ;

Zhuang, Gui-Lin ;

Fan, Liming ;

Zhang, Xiutang ;

Gao, Lin-Na ;

Sun, Di .

CHEMICAL COMMUNICATIONS, 2020, 56 (13) :2047-2050

[7] Benchmark C2H2/CO2 and CO2/C2H2 Separation by Two Closely Related Hybrid Ultramicroporous Materials [J].

Chen, Kai-Jie ;

Scott, Hayley S. ;

Madden, David G. ;

Pham, Tony ;

Kumar, Amrit ;

Bajpai, Alankriti ;

Lusi, Matteo ;

Forrest, Katherine A. ;

Space, Brian ;

Perry, John J. ;

Zaworotko, Michael J. .

CHEM, 2016, 1 (05) :753-765

[8] Pore chemistry and size control in hybrid porous materials for acetylene capture from ethylene [J].

Cui, Xili ;

Chen, Kaijie ;

Xing, Huabin ;

Yang, Qiwei ;

Krishna, Rajamani ;

Bao, Zongbi ;

Wu, Hui ;

Zhou, Wei ;

Dong, Xinglong ;

Han, Yu ;

Li, Bin ;

Ren, Qilong ;

Zaworotko, Michael J. ;

Chen, Banglin .

SCIENCE, 2016, 353 (6295) :141-144

[9] A fluorine-functionalized microporous In-MOF with high physicochemical stability for light hydrocarbon storage and separation [J].

Fan, Weidong ;

Liu, Xiuping ;

Wang, Xia ;

Li, Yue ;

Xing, Chengyong ;

Wang, Yutong ;

Guo, Wenyue ;

Zhang, Liangliang ;

Sun, Daofeng .

INORGANIC CHEMISTRY FRONTIERS, 2018, 5 (10) :2445-2449

[10] Destruction of Metal-Organic Frameworks: Positive and Negative Aspects of Stability and Lability [J].

Feng, Liang ;

Wang, Kun-Yu ;

Day, Gregory S. ;

Ryder, Matthew R. ;

Zhou, Hong-Cai .

CHEMICAL REVIEWS, 2020, 120 (23) :13087-13133

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