Regioselective hydrostannation of allenes catalyzed by Pd(OH)(2)/C

被引：14

作者：

Lautens, M

Ostrovsky, D

Tao, B

机构：

[1] Department of Chemistry, University of Toronto, Toronto

来源：

TETRAHEDRON LETTERS | 1997年 / 38卷 / 36期

基金：

加拿大自然科学与工程研究理事会;

关键词：

D O I：

10.1016/S0040-4039(97)01459-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A series of mono-substituted allenes 1-7 were shown to undergo regioselective hydrostannation when treated with Bu3SnH in the presence of Pd(OH)(2)/C in THF to give the vinyl stannanes 11-17. The use of Pd(PPh3)(4), led to regioisomeric mixtures of allyl stannanes. (C) 1997 Elsevier Science Ltd.

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页码：6343 / 6346

页数：4

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