Switching the Electron-Donor Properties of N-Heterocyclic Carbenes by a Facile Deprotonation Strategy

被引：89

作者：

Biju, Akkattu T. ^{[1
]}

Hirano, Keiichi ^{[1
]}

Froehlich, Roland ^{[1
]}

Glorius, Frank ^{[1
]}

机构：

[1] Univ Munster, Inst Organ Chem, D-48149 Munster, Germany

来源：

CHEMISTRY-AN ASIAN JOURNAL | 2009年 / 4卷 / 12期

关键词：

carbenes; electronic properties; enolates; heterocycles; ligand design; RESTRICTED FLEXIBILITY; LIGANDS; COMPLEXES; CATALYSTS;

D O I：

10.1002/asia.200900410

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Flip the switch! The facile and distinct variation of the electronic properties of an N-heterocyclic carbene (NHC) ligand is reported. In this process, a simple deprotonation/protonation strategy can render the NHC to be an electron-poor or an electron-rich NHC ligand: one ligand, two electronic natures. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：1786 / 1789

页数：4

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