A simple and convenient method for the synthesis of pyranoid glycals

被引：39

作者：

Zhao, Jinzhong ^{[1
,2
,3
]}

Wei, Shanqiao ^{[1
,3
]}

Ma, Xiaofeng ^{[1
,3
]}

Shao, Huawu ^{[1
]}

机构：

[1] Chinese Acad Sci, Chengdu Inst Biol, Nat Prod Res Ctr, Chengdu 610041, Peoples R China

[2] Shanxi Agr Univ, Taigu 030801, Shanxi, Peoples R China

[3] Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China

来源：

CARBOHYDRATE RESEARCH | 2010年 / 345卷 / 01期

关键词：

Glycals; Phosphate buffer; Glycopyranosyl bromides; Zinc; Reductive elimination; 1,2-CYCLOPROPANATED SUGARS; STEREOSELECTIVE-SYNTHESIS; CHROMIUM(II) COMPLEXES; GLYCOSYL BROMIDES; FURANOID GLYCALS; C-GLYCOSIDATION; EFFICIENT; DONORS; DERIVATIVES; NITROGEN;

D O I：

10.1016/j.carres.2009.10.003

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

A simple, mild, and environmentally benign synthesis procedure of pyranoid glycals is described. In a novel fashion, protected glycopyramosyl bromides undergo the reductive elimination in the presence of zinc in phosphate buffer at room temperature. The pyranoid glycals were obtained in good-to-excel lent yields (18 examples). (C) 2009 Elsevier Ltd. All rights reserved.

引用

页码：168 / 171

页数：4

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