Role of bright and dark excitons in the temperature-dependent photoluminescence of carbon nanotubes

被引:111
作者
Mortimer, I. B. [1 ]
Nicholas, R. J. [1 ]
机构
[1] Univ Oxford, Clarendon Lab, Dept Phys, Oxford OX1 3PU, England
基金
英国工程与自然科学研究理事会;
关键词
D O I
10.1103/PhysRevLett.98.027404
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
We report studies of the temperature dependence of the photoluminescence efficiency of single walled carbon nanotubes which demonstrate the role of bright and dark excitons. This is determined by the energy splitting of the excitons combined with 1-D excitonic properties. The splitting of the bright and dark singlet exciton states is found to be only a few meV and is very strongly diameter dependent for diameters in the range 0.8-1.2 nm. The luminescence intensities are also found to be strongly enhanced by magnetic fields at low temperatures due to mixing of the exciton states.
引用
收藏
页数:4
相关论文
共 33 条
[1]   ELECTRONIC STATES OF CARBON NANOTUBES [J].
AJIKI, H ;
ANDO, T .
JOURNAL OF THE PHYSICAL SOCIETY OF JAPAN, 1993, 62 (04) :1255-1266
[2]   Effects of valley mixing and exchange on excitons in carbon nanotubes with Aharonov-Bohm flux [J].
Ando, T .
JOURNAL OF THE PHYSICAL SOCIETY OF JAPAN, 2006, 75 (02)
[3]   Excitons in carbon nanotubes [J].
Ando, T .
JOURNAL OF THE PHYSICAL SOCIETY OF JAPAN, 1997, 66 (04) :1066-1073
[4]   Matrix-imposed stress-induced shifts in the photoluminescence of single-walled carbon nanotubes at low temperatures [J].
Arnold, K ;
Lebedkin, S ;
Kiowski, O ;
Hennrich, F ;
Kappes, MM .
NANO LETTERS, 2004, 4 (12) :2349-2354
[5]   Structure-assigned optical spectra of single-walled carbon nanotubes [J].
Bachilo, SM ;
Strano, MS ;
Kittrell, C ;
Hauge, RH ;
Smalley, RE ;
Weisman, RB .
SCIENCE, 2002, 298 (5602) :2361-2366
[6]   Electromechanical properties of metallic, quasimetallic, and semiconducting carbon nanotubes under stretching [J].
Cao, J ;
Wang, Q ;
Dai, HJ .
PHYSICAL REVIEW LETTERS, 2003, 90 (15) :4
[7]   Temperature dependence of the band gap of semiconducting carbon nanotubes [J].
Capaz, RB ;
Spataru, CD ;
Tangney, P ;
Cohen, ML ;
Louie, SG .
PHYSICAL REVIEW LETTERS, 2005, 94 (03)
[8]   Hydrostatic pressure effects on the structural and electronic properties of carbon nanotubes [J].
Capaz, RB ;
Spataru, CD ;
Tangney, P ;
Cohen, ML ;
Louie, SG .
PHYSICA STATUS SOLIDI B-BASIC SOLID STATE PHYSICS, 2004, 241 (14) :3352-3359
[9]   Excitons in carbon nanotubes:: An ab initio symmetry-based approach -: art. no. 196401 [J].
Chang, E ;
Bussi, G ;
Ruini, A ;
Molinari, E .
PHYSICAL REVIEW LETTERS, 2004, 92 (19) :196401-1
[10]  
CHANG E, CONDMAT0603085