Intramolecular Hydrogen-Bond Activation: Strategies, Benefits, and Influence in Catalysis

被引：18
|
作者：
Guerrero-Corella, Andrea [1 ]
Fraile, Alberto [1 ,2 ]
Aleman, Jose [1 ,2 ]
机构：
[1] Univ Autonoma Madrid, Dept Organ Chem, Modulo 1, Madrid 28049, Spain
[2] Univ Autonoma Madrid, Inst Adv Res Chem Sci IAdChem, Madrid 28049, Spain
来源：
ACS ORGANIC & INORGANIC AU | 2022年 / 2卷 / 03期
基金：
欧洲研究理事会;
关键词：
intramolecular activation; hydrogen bonding; organocatalysis; metal catalysis; bifunctional catalysis; asymmetric synthesis; ENANTIOSELECTIVE TRANSFER HYDROGENATION; AZOMETHINE YLIDES; MICHAEL ADDITION; CYCLOADDITION; IMINES; DONORS;
D O I：
10.1021/acsorginorgau.1c00053
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The activation of molecules through intramolecular hydrogen-bond formation to promote chemical reactions appears as a suitable strategy in organic synthesis, especially for the preparation of chiral compounds under metal and organocatalytic conditions. The use of this interaction has enabled reactivity enhancement of reagents, as well as stabilization of the chemical species and enantiocontrol of the processes.
引用
收藏
页码：197 / 204
页数：8
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