Intramolecular Hydrogen-Bond Activation: Strategies, Benefits, and Influence in Catalysis

被引：18
|
作者：
Guerrero-Corella, Andrea [1 ]
Fraile, Alberto [1 ,2 ]
Aleman, Jose [1 ,2 ]
机构：
[1] Univ Autonoma Madrid, Dept Organ Chem, Modulo 1, Madrid 28049, Spain
[2] Univ Autonoma Madrid, Inst Adv Res Chem Sci IAdChem, Madrid 28049, Spain
来源：
ACS ORGANIC & INORGANIC AU | 2022年 / 2卷 / 03期
基金：
欧洲研究理事会;
关键词：
intramolecular activation; hydrogen bonding; organocatalysis; metal catalysis; bifunctional catalysis; asymmetric synthesis; ENANTIOSELECTIVE TRANSFER HYDROGENATION; AZOMETHINE YLIDES; MICHAEL ADDITION; CYCLOADDITION; IMINES; DONORS;
D O I：
10.1021/acsorginorgau.1c00053
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The activation of molecules through intramolecular hydrogen-bond formation to promote chemical reactions appears as a suitable strategy in organic synthesis, especially for the preparation of chiral compounds under metal and organocatalytic conditions. The use of this interaction has enabled reactivity enhancement of reagents, as well as stabilization of the chemical species and enantiocontrol of the processes.
引用
收藏
页码：197 / 204
页数：8
相关论文
共 50 条
  • [21] INTRAMOLECULAR HYDROGEN-BOND AND DIPOLE-MOMENTS .4. INTRAMOLECULAR HYDROGEN-BOND AND DIPOLE-MOMENTS OF OMEGA-CHLOROALKANOLS
    TOSHIYASU, Y
    FUJISHIR.R
    NIPPON KAGAKU KAISHI, 1973, (03) : 622 - 623
  • [22] TWO-DIMENSIONAL MODEL OF INTRAMOLECULAR HYDROGEN-BOND
    ISHENKO, SI
    VENER, MV
    MAMAEV, VM
    THEORETICA CHIMICA ACTA, 1985, 68 (05): : 351 - 362
  • [23] INTRAMOLECULAR HYDROGEN-BOND AND ELECTRICAL-PROPERTIES OF MOLECULES
    PREZHDO, VV
    VASHCHENKO, EV
    PREZHDO, OV
    KHIMICHESKAYA FIZIKA, 1993, 12 (07): : 883 - 896
  • [24] Intramolecular hydrogen-bond participation in phosphonylammonium salt formation
    Smith, AB
    Ducry, L
    Corbett, RM
    Hirschmann, R
    ORGANIC LETTERS, 2000, 2 (24) : 3887 - 3890
  • [25] INTRAMOLECULAR HYDROGEN-BOND AND CONFORMATIONS OF HYDROXYCARBOXYLIC ACIDS ESTERS
    GINZBURG, IM
    STRELKOVA, LF
    ZHURNAL OBSHCHEI KHIMII, 1993, 63 (04): : 762 - 767
  • [26] NH SE INTRAMOLECULAR HYDROGEN-BOND IN PYRAZOLONE DERIVATIVES
    KURKOVSKAYA, LN
    KOSHELEV, YN
    KVITKO, IY
    SHAPETKO, NN
    ZHURNAL ORGANICHESKOI KHIMII, 1972, 8 (01): : 215 - +
  • [27] ELECTRONIC MODEL OF HYDROGEN-BONDING AND CONSISTENT INFLUENCE OF COMPOUND AND FORMATION OF MOLECULES ON INTRAMOLECULAR HYDROGEN-BOND
    LUTSKII, AE
    DOLZHENKO, YI
    ZHURNAL OBSHCHEI KHIMII, 1980, 50 (02): : 440 - 446
  • [28] Organo-Polyoxometalate-Based Hydrogen-Bond Catalysis
    Vilona, Debora
    Lelli, Moreno
    Dumont, Elise
    Lacote, Emmanuel
    CHEMISTRY-A EUROPEAN JOURNAL, 2021, 27 (71) : 17761 - 17764
  • [29] INFLUENCE OF SUBSTITUENTS ON HYDROGEN-BOND IN DIBENZOYLMETHANES
    BRATAN, S
    STROHBUS.F
    CHEMISCHE BERICHTE-RECUEIL, 1972, 105 (07): : 2284 - &
  • [30] Intramolecular hydrogen-bond activation for the addition of nucleophilic imines: 2-hydroxybenzophenone as a chemical auxiliary
    Choubane, Houcine
    Garrido-Castro, Alberto F.
    Alvarado, Cuauhtemoc
    Martin-Somer, Ana
    Guerrero-Corella, Andrea
    Daaou, Mortada
    Diaz-Tendero, Sergio
    Carmen Maestro, M.
    Fraile, Alberto
    Aleman, Jose
    CHEMICAL COMMUNICATIONS, 2018, 54 (27) : 3399 - 3402
12345