Water absorption and moisture permeation properties of chitosan/poly(acrylamide-co-itaconic acid) IPC films

被引:45
作者
Bajpai, M. [1 ]
Bajpai, S. K. [1 ]
Jyotishi, Pooja [1 ]
机构
[1] Govt Model Sci Coll, Polymer Res Lab, Dept Chem, Jabalpur 482001, MP, India
关键词
Polyelectrolyte complex films; Swelling; pH; Water vapor transmission rate; Hydrogels; DRUG-DELIVERY; POLYELECTROLYTE COMPLEXES; MOLECULAR-WEIGHT; WOUND DRESSINGS; IN-VITRO; CHITOSAN; HYDROGELS; DISSOLUTION; COMPOSITES; SCAFFOLDS;
D O I
10.1016/j.ijbiomac.2015.11.088
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
In this work, aqueous solutions of chitosan (Ch) and [poly(acrylamide(AAm)-co-itaconicacid(IA)1 have been mixed to yield Ch/poly(AAm-co-IA) Inter-polyelectrolyte complex (IPC) films. The films were characterized by FTIR, X-ray diffraction (XRD) and thermo gravimetric analysis (TGA). There was remarkable increase in the crystalline nature of IPC films. The films were investigated for their water absorption capacity in the physiological fluid (PF) of pH 7.4 at 37 degrees C. The amount of IA present in the film forming solutions affected the water absorption behavior of the resulting films. The dynamic water uptake data were interpreted by various kinetic models. The effect of pH on the swelling ratio (SR) indicated that the films showed highest swelling in lower as well as higher pH media. The water vapor transmission rates (WVTR) were obtained in the range of 6000-6645 g/m(2)/day. (C) 2015 Elsevier B.V. All rights reserved.
引用
收藏
页码:1 / 9
页数:9
相关论文
共 52 条
[1]   Chitosan-PVP-nano silver oxide wound dressing: In vitro and in vivo evaluation [J].
Archana, D. ;
Singh, Brijesh K. ;
Dutta, Joydeep ;
Dutta, P. K. .
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES, 2015, 73 :49-57
[2]   Investigation of curcumin release from chitosan/cellulose micro crystals (CMC) antimicrobial films [J].
Bajpai, S. K. ;
Chand, Navin ;
Ahuja, Sonam .
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES, 2015, 79 :440-448
[3]  
Balkhande J. V., 2014, INT J ENG SCI INNOV, V3, P300
[4]   Swelling behavior of chitosan/pectin polyelectrolyte complex membranes.: Effect of thermal cross-linking [J].
Bernabé, P ;
Peniche, C ;
Argüelles-Monal, W .
POLYMER BULLETIN, 2005, 55 (05) :367-375
[5]   Synthesis and characterization of novel pH-sensitive chitosan-poly(acrylamide-co-itaconic acid) hydrogels [J].
Bocourt, Michel ;
Bada, Nancy ;
Acosta, Niuris ;
Bucio, Emilio ;
Peniche, Carlos .
POLYMER INTERNATIONAL, 2014, 63 (09) :1715-1723
[6]  
Caykara Tuncer, 2004, NETWORK J POLYM SC B, V4213, P2586
[7]   EFFECTS OF MOLECULAR-WEIGHT AND PLASTICIZATION ON DISSOLUTION RATES OF THIN POLYMER-FILMS [J].
COOPER, WJ ;
KRASICKY, PD ;
RODRIGUEZ, F .
POLYMER, 1985, 26 (07) :1069-1072
[8]   Development of natural-based wound dressings impregnated with bioactive compounds and using supercritical carbon dioxide [J].
Dias, A. M. A. ;
Braga, M. E. M. ;
Seabra, I. J. ;
Ferreira, P. ;
Gil, M. H. ;
de Sousa, H. C. .
INTERNATIONAL JOURNAL OF PHARMACEUTICS, 2011, 408 (1-2) :9-19
[9]   Acceleration of dermal wound healing by using electrospun curcumin-loaded poly(ε-caprolactone)-poly(ethylene glycol)-poly(ε-caprolactone) fibrous mats [J].
Fu, Shao-Zhi ;
Meng, Xiao-Hang ;
Fan, Juan ;
Yang, Ling-Lin ;
Wen, Qing-Lian ;
Ye, Su-Juan ;
Lin, Sheng ;
Wang, Bi-Qiong ;
Chen, Lan-Lan ;
Wu, Jing-Bo ;
Chen, Yue ;
Fan, Jun-Ming ;
Li, Zhi .
JOURNAL OF BIOMEDICAL MATERIALS RESEARCH PART B-APPLIED BIOMATERIALS, 2014, 102 (03) :533-542
[10]   Development and characterisation of a new biodegradable edible film made from kefiran, an exopolysaccharide obtained from kefir grains [J].
Ghasemlou, Mehran ;
Khodaiyan, Faramarz ;
Oromiehie, Abdulrasoul ;
Yarmand, Mohammad Saeid .
FOOD CHEMISTRY, 2011, 127 (04) :1496-1502