The experimental determination of Th(iv)/Th(iii) redox potentials in organometallic thorium complexes

被引：21
作者：
Inman, Christopher J. [1 ]
Cloke, F. Geoffrey N. [1 ]
机构：
[1] Univ Sussex, Sch Life Sci, Dept Chem, Brighton BN1 9QJ, E Sussex, England
来源：
DALTON TRANSACTIONS | 2019年 / 48卷 / 29期
基金：
英国工程与自然科学研究理事会;
关键词：
HYDRIDE CHEMISTRY; ACTIVATION; LIGANDS; CO2;
D O I：
10.1039/c9dt01553a
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The first Th-IV/Th-III redox couple values have been determined experimentally using cyclic voltammetry (CV), which has been facilitated by the use of [(Bu4N)-Bu-n][BPh4] as a supporting electrolyte in THF. Th(iv) and Th(iii) metallocene compounds have been studied and their redox couple values are in the range of -2.96 V to -3.32 V vs FeCp2+/0.
引用
收藏
页码：10782 / 10784
页数：3
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