Tailoring the Adsorption and Reaction Chemistry of the Metal -Organic Frameworks UiO-66, UiO-66-NH2, and HKUST-1 via the Incorporation of Molecular Guests

被引:46
作者
Ploskonka, Ann M. [1 ]
DeCoste, Jared B. [2 ]
机构
[1] Leidos Inc, Edgewood Chem Biol Ctr, POB 68, Aberdeen Proving Ground, MD 21010 USA
[2] US Army Res Dev & Engn Command, Edgewood Chem Biol Ctr, 5183 Blackhawk Rd, Aberdeen Proving Ground, MD 21010 USA
关键词
metal-organic frameworks; catalysis; adsorption; chemical warfare agents; toxic industrial chemicals; FACILE SYNTHESIS; WATER STABILITY; DRUG-DELIVERY; PORE-SIZE; SCALE-UP; REMOVAL; MOFS; GAS; FUNCTIONALITY; DEGRADATION;
D O I
10.1021/acsami.7b06274
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Metal-organic frameworks (MOFs) are versatile materials highly regarded for their porous nature. Depending on the synthetic Method, various guest molecules may remain in the pores or can be systematically loaded for various reasons. Herein, we present a study that explores the effect of guest molecules on the adsorption and reactivity of the MOF in both the gas phase and solution. The differences between guest molecule interactions and the subsequent effects on their activity are described for each system. Interestingly, different effects are observed and described in detail for each class of guest molecules studied. We determine that there is a strong effect of alcohols with the secondary building unit of UiO MOFs, While Lewis bases have an effect on the reactivity of the -NH2 group in UiO-66-NH2 and adsorption by the coordinatively unsaturated copper sites in HKUST-1. These effects must be considered when deter mining synthesis and activation methods, of MOFs toward various applications.
引用
收藏
页码:21579 / 21585
页数:7
相关论文
共 41 条
[1]   One-pot synthesis of binary metal organic frameworks (HKUST-1 and UiO-66) for enhanced adsorptive removal of water contaminants [J].
Azhar, Muhammad Rizwan ;
Abid, Hussein Rasool ;
Sun, Hongqi ;
Periasamy, Vijay ;
Tade, Moses O. ;
Wang, Shaobin .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2017, 490 :685-694
[2]   Filtration of chlorine and hydrogen chloride gas by engineered UiO-66-NH2 metal-organic framework [J].
Browe, Matthew A. ;
Napolitano, Amedeo ;
DeCoste, Jared B. ;
Peterson, Gregory W. .
JOURNAL OF HAZARDOUS MATERIALS, 2017, 332 :162-167
[3]   Water Stability and Adsorption in Metal-Organic Frameworks [J].
Burtch, Nicholas C. ;
Jasuja, Himanshu ;
Walton, Krista S. .
CHEMICAL REVIEWS, 2014, 114 (20) :10575-10612
[4]   Synthesis, characterization and adsorption ability of UiO-66-NH2 [J].
Cam Loc Luu ;
Thi Thuy Van Nguyen ;
Tri Nguyen ;
Tien Cuong Hoang .
ADVANCES IN NATURAL SCIENCES-NANOSCIENCE AND NANOTECHNOLOGY, 2015, 6 (02)
[5]   A new zirconium inorganic building brick forming metal organic frameworks with exceptional stability [J].
Cavka, Jasmina Hafizovic ;
Jakobsen, Soren ;
Olsbye, Unni ;
Guillou, Nathalie ;
Lamberti, Carlo ;
Bordiga, Silvia ;
Lillerud, Karl Petter .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (42) :13850-13851
[6]   Luminescent Functional Metal-Organic Frameworks [J].
Cui, Yuanjing ;
Yue, Yanfeng ;
Qian, Guodong ;
Chen, Banglin .
CHEMICAL REVIEWS, 2012, 112 (02) :1126-1162
[7]   Removal of chlorine gas by an amine functionalized metal-organic framework via electrophilic aromatic substitution [J].
DeCoste, Jared B. ;
Browe, Matthew A. ;
Wagner, George W. ;
Rossin, Joseph A. ;
Peterson, Gregory W. .
CHEMICAL COMMUNICATIONS, 2015, 51 (62) :12474-12477
[8]   The effect of water adsorption on the structure of the carboxylate containing metal-organic frameworks Cu-BTC, Mg-MOF-74, and UiO-66 [J].
DeCoste, Jared B. ;
Peterson, Gregory W. ;
Schindler, Bryan J. ;
Killops, Kato L. ;
Browe, Matthew A. ;
Mahle, John J. .
JOURNAL OF MATERIALS CHEMISTRY A, 2013, 1 (38) :11922-11932
[9]   Stability and degradation mechanisms of metal-organic frameworks containing the Zr6O4(OH)4 secondary building unit [J].
DeCoste, Jared B. ;
Peterson, Gregory W. ;
Jasuja, Himanshu ;
Glover, T. Grant ;
Huang, You-gui ;
Walton, Krista S. .
JOURNAL OF MATERIALS CHEMISTRY A, 2013, 1 (18) :5642-5650
[10]   Systematic design of pore size and functionality in isoreticular MOFs and their application in methane storage [J].
Eddaoudi, M ;
Kim, J ;
Rosi, N ;
Vodak, D ;
Wachter, J ;
O'Keeffe, M ;
Yaghi, OM .
SCIENCE, 2002, 295 (5554) :469-472