Synthesis, Luminescence and Nonlinear Optical Properties of Homoleptic Tetracyanamidogermanates ARE[Ge(CN2)4] (A = K, Cs, and RE = La, Ce, Pr, Nd, Sm, Eu, Gd)

被引：10

作者：

Dolabdjian, Konstantin ^{[1
]}

Schedel, Christine ^{[1
]}

Enseling, David ^{[2
]}

Juestel, Thomas ^{[2
]}

Meyer, Hans-Juergen ^{[1
]}

机构：

[1] Univ Tubingen, Inst Anorgan Chem, Abt Festkorperchem & Theoret Anorgan Chem, Morgenstelle 18, D-72076 Tubingen, Germany

[2] FH Munster, Fachbereich Chem Ingn, Stegerwaldstr 39, D-48565 Steinfurt, Germany

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2017年 / 643卷 / 07期

关键词：

Cyanamidometallate; Luminescence; Solid-state metathesis; Non-linear optics; Rare earth; CRYSTAL-STRUCTURE; MAGNETIC-PROPERTIES; CARBODIIMIDE; PHOTOLUMINESCENCE; TRANSITION; D-5(0);

D O I：

10.1002/zaac.201600353

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two new series of tetracyanamidogermanates were prepared by solid-state reaction of appropriate amounts of REF3 (RE = rare earth), A(2)[GeF6] (A = alkaline), and Li-2(CN2) in evacuated silica tubes. Powder X-ray diffraction patterns of crystalline samples of KRE[Ge(CN2)(4)] and CsRE[Ge(CN2)(4)] were indexed isotypically to KRE[Si(CN2)(4)] and RbRE[Ge(CN2)(4)], respectively. Luminescence properties of Ce3+, Eu3+, and Tb3+ doped compounds and non-linear optical properties (NLO) of KRE[Ge(CN2)(4)] are reported.

引用

页码：488 / 494

页数：7

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