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Pressure-induced transformations in crystalline and vitreous PbGeO3
被引:1
|作者:
Oelker, Erin N.
[1
]
Bhat, M. Harish
[1
]
Soignard, Emmanuel
[1
]
Yarger, Jeffery L.
[1
]
机构:
[1] Arizona State Univ, Dept Chem & Biochem, Tempe, AZ 85287 USA
关键词:
Disordered systems;
Phase transitions;
INDUCED AMORPHIZATION;
RAMAN-SCATTERING;
GLASSES;
TRANSITION;
PBO-GEO2;
PHASE;
SIO2;
D O I:
10.1016/j.ssc.2009.07.052
中图分类号:
O469 [凝聚态物理学];
学科分类号:
070205 ;
摘要:
Structural transitions in crystalline and vitreous PbGeO3 were studied at pressures up to 20 GPa. Crystalline PbGeO3 was observed to undergo a pressure-induced amorphization between 12-18 GPa. Vitreous PbGeO3 was found to exhibit an amorphous-to-amorphous transition in a similar pressure range. The structural and thermal properties of the pressure-cycled PbGeO3 materials were further studied with high-energy x-ray diffraction and differential scanning calorimetry. The properties were then compared to those of thermally quenched glass and ball-milled PbGeO3 samples. The structure of pressure-amorphized PbGeO3 was found to closely resemble that of ball-milled PbGeO3. However, the thermal properties probed by differential scanning calorimetry exhibited significant differences to those of thermally quenched PbGeO3 glass. (C) 2009 Elsevier Ltd. All rights reserved.
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页码:1940 / 1943
页数:4
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