Corrosion behavior of 316L stainless steel and Zr75Ti25 bulk amorphous alloy in simulated PEMFC anode environment in a solution containing 12.5 ppm H2SO4+1.8 ppm HF at 25 and 80°C

被引：16
作者：
Jin, Shize [1 ]
Ghali, Edward
Morales, Arianna T.
机构：
[1] Univ Laval, Dept Min Met & Mat Engn, Ste Foy, PQ G1K 7P4, Canada
[2] Gen Motors R&D Ctr, Mat & Proc Lab, Warren, MI 48090 USA
来源：
JOURNAL OF POWER SOURCES | 2006年 / 162卷 / 01期
关键词：
stainless steel; amorphous alloy; corrosion; electrochemical impedance;
D O I：
10.1016/j.jpowsour.2006.06.060
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Metallic alloys have been considered for the fabrication of bipolar plates for polymer electrolyte membrane fuel cells (PEMFC). The corrosion behavior of 316L stainless steel (31-6L) and Zr75Ti25 bulk amorphous alloy (AB) in PEMFC environments was studied using polarization resistance and electrochemical impedance spectroscopy (EIS) methods. The results showed that under natural corrosion conditions, the amorphous bulk alloy had a corrosion resistance close to that of 316L stainless steel. In all other fuel cell environments studied, the corrosion rate of AB was lower than that of 316L. (c) 2006 Elsevier B.V. All rights reserved.
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页码：294 / 301
页数：8
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