Catalytic conversion of xylose and corn stalk into furfural over carbon solid acid catalyst in γ-valerolactone

被引：138

作者：

Zhang, Tingwei ^{[1
]}

Li, Wenzhi ^{[1
]}

Xu, Zhiping ^{[2
]}

Liu, Qiyu ^{[1
]}

Ma, Qiaozhi ^{[1
]}

Jameel, Hasan ^{[3
]}

Chang, Hou-min ^{[3
]}

Ma, Longlong ^{[4
]}

机构：

[1] Univ Sci & Technol China, Dept Thermal Sci & Energy Engn, Hefei 230026, Peoples R China

[2] Univ Sci & Technol China, Dept Chem, Hefei 230026, Peoples R China

[3] N Carolina State Univ, Dept Forest Biomat, Raleigh, NC 27695 USA

[4] Chinese Acad Sci, Guangzhou Inst Energy Convers, CAS Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China

来源：

BIORESOURCE TECHNOLOGY | 2016年 / 209卷

关键词：

Xylose; Corn stalk; Furfural; Carbon solid acid; gamma-Valerolactone; DEHYDRATION; HYDROGENATION; LIGNIN; XYLAN; HYDROLYSIS; CELLULOSE; BIOMASS; STOVER;

D O I：

10.1016/j.biortech.2016.02.108

中图分类号：

S2 [农业工程];

学科分类号：

0828 ;

摘要：

A novel carbon solid acid catalyst was synthesized by the sulfonation of carbonaceous material which was prepared by carbonization of sucrose using 4-BDS as a sulfonating agent. TEM, N-2 adsorption-desorption, elemental analysis, XPS and FT-IR were used to characterize the catalyst. Then, the catalyst was applied for the conversion of xylose and corn stalk into furfural in GVL. The influence of the reaction time, temperature and dosage of catalyst on xylose dehydration were also investigated. The Bronsted acid catalyst exhibited high activity in the dehydration of xylose, with a high furfural yield of 78.5% at 170 degrees C in 30 min. What's more, a 60.6% furfural yield from corn stalk was achieved in 100 min at 200 degrees C. The recyclability of the sulfonated carbon catalyst was perfect, and it could be reused for 5 times without the loss of furfural yields. (C) 2016 Elsevier Ltd. All rights reserved.

引用

页码：108 / 114

页数：7

共 35 条

[11] Efficient carbon-based solid acid catalysts for the esterification of oleic acid [J].

Geng, Liang ;

Wang, Yu ;

Yu, Gang ;

Zhu, Yuexiang .

CATALYSIS COMMUNICATIONS, 2011, 13 (01) :26-30

[12] Conversion of Hemicellulose into Furfural Using Solid Acid Catalysts in γ-Valerolactone [J].

Guerbuez, Elif I. ;

Gallo, Jean Marcel R. ;

Alonso, David Martin ;

Wettstein, Stephanie G. ;

Lim, Wee Y. ;

Dumesic, James A. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2013, 52 (04) :1270-1274

[13] Conversion of fructose and glucose into 5-hydroxymethylfurfural with lignin-derived carbonaceous catalyst under microwave irradiation in dimethyl sulfoxide-ionic liquid mixtures [J].

Guo, Feng ;

Fang, Zhen ;

Zhou, Tie-Jun .

BIORESOURCE TECHNOLOGY, 2012, 112 :313-318

[14] Sulfonated graphene as water-tolerant solid acid catalyst [J].

Ji, Junyi ;

Zhang, Guanghui ;

Chen, Hongyu ;

Wang, Shulan ;

Zhang, Guoliang ;

Zhang, Fengbao ;

Fan, Xiaobin .

CHEMICAL SCIENCE, 2011, 2 (03) :484-487

[15] Characterization of Hydrochars Produced by Hydrothermal Carbonization of Lignin, Cellulose, D-Xylose, and Wood Meal [J].

Kang, Shimin ;

Li, Xianglan ;

Fan, Juan ;

Chang, Jie .

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2012, 51 (26) :9023-9031

[16] Carbocatalytic dehydration of xylose to furfural in water [J].

Lam, Edmond ;

Chong, Jonathan H. ;

Majid, Ehsan ;

Liu, Yali ;

Hrapovic, Sabahudin ;

Leung, Alfred C. W. ;

Luong, John H. T. .

CARBON, 2012, 50 (03) :1033-1043

[17] Synthesis of Furfural from Xylose by Heterogeneous and Reusable Nafion Catalysts [J].

Lam, Edmond ;

Majid, Ehsan ;

Leung, Alfred C. W. ;

Chong, Jonathan H. ;

Mahmoud, Khaled A. ;

Luong, John H. T. .

CHEMSUSCHEM, 2011, 4 (04) :535-541

[18] FurfuraluA Promising Platform for Lignocellulosic Biofuels [J].

Lange, Jean-Paul ;

van der Heide, Evert ;

van Buijtenen, Jeroen ;

Price, Richard .

CHEMSUSCHEM, 2012, 5 (01) :150-166

[19] High Yield Conversion of Residual Pentoses into Furfural via Zeolite Catalysis and Catalytic Hydrogenation of Furfural to 2-Methylfuran [J].

Lessard, Jean ;

Morin, Jean-Francois ;

Wehrung, Jean-Francois ;

Magnin, Delphine ;

Chornet, Esteban .

TOPICS IN CATALYSIS, 2010, 53 (15-18) :1231-1234

[20]

Li H. L., 2014, BIORESOURCE TECHNOL, V102, P7371

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