Composting of Polylactide Containing Natural Anti-Aging Compounds of Plant Origin

被引:11
作者
Moraczewski, Krzysztof [1 ]
Malinowski, Rafal [2 ]
Sikorska, Wanda [3 ]
Karasiewicz, Tomasz [1 ]
Stepczynska, Magdalena [1 ]
Jagodzinski, Bartlomiej [1 ]
Rytlewski, Piotr [1 ]
机构
[1] Kazimierz Wielki Univ, Inst Mat Engn, Chodkiewicza 30, PL-85064 Bydgoszcz, Poland
[2] Lukasiewicz Res Network, Inst Engn Polymer Mat & Dyes, Marii Sklodowskiej Curie 55, PL-87100 Torun, Poland
[3] Polish Acad Sci, Ctr Polymer & Carbon Mat, Marii Curie Sklodowskiej 34, PL-41819 Zabrze, Poland
关键词
polylactide; plant extracts; polyphenols; biodegradation; ACID PLA; HYDROLYTIC DEGRADATION; POLY(LACTIC ACID); ANTIOXIDANT; BHT; POLYPROPYLENE; POLYETHYLENE; STABILIZERS; IRRADIATION; RELEASE;
D O I
10.3390/polym11101582
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The paper presents the effects of biodegradation of polylactide containing natural anti-aging compounds. Polymer containing 0.5; 5 and 10 wt % of coffee, cocoa or cinnamon extracts were subjected to industrial composting for 7, 14, 21 or 28 days. The effect of the composting process on polylactide properties was examined based on visual assessment, scanning electron microscopy, average molecular weight, differential scanning calorimetry, thermogravimetry, and tensile strength. The impact of the tested extracts on the effects of the composting process was compared with the impact of a commercially available anti-aging compound. It was found that the tested extracts in most cases did not adversely affect the effects of the composting process compared to pure polylactide, often resulting in intensification of biodegradation processes. As a result of the composting process, changes in the macro- and microscopic appearance of the samples and a decrease in molecular weight, phase transition temperatures, thermal resistance, and thermal strength were observed on a scale close to or greater than the reference anti-aging compound.
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页数:19
相关论文
共 40 条
[1]   Antioxidant and antilisterial activity of olive oil, cocoa and rosemary extract polyphenols [J].
Bubonja-Sonje, Marina ;
Giacometti, Jasminka ;
Abram, Maja .
FOOD CHEMISTRY, 2011, 127 (04) :1821-1827
[2]   Characterization of an antioxidant polylactic acid (PLA) film prepared with α-tocopherol, BHT and polyethylene glycol using film cast extruder [J].
Byun, Youngjae ;
Kim, Young Teck ;
Whiteside, Scott .
JOURNAL OF FOOD ENGINEERING, 2010, 100 (02) :239-244
[3]   Insights on the aerobic biodegradation of polymers by analysis of evolved carbon dioxide in simulated composting conditions [J].
Castro-Aguirre, E. ;
Auras, R. ;
Selke, S. ;
Rubino, M. ;
Marsh, T. .
POLYMER DEGRADATION AND STABILITY, 2017, 137 :251-271
[4]   Hydrolytic degradation of polylactic acid (PLA) and its composites [J].
Elsawy, Moataz A. ;
Kim, Ki-Hyun ;
Park, Jae-Woo ;
Deep, Akash .
RENEWABLE & SUSTAINABLE ENERGY REVIEWS, 2017, 79 :1346-1352
[5]  
Epstein E., 1997, SCI COMPOSTING
[6]   Composition dependence of the synergistic effect of nucleating agent and plasticizer in poly(lactic acid): A Mixture Design study [J].
Fehri, M. K. ;
Mugoni, C. ;
Cinelli, P. ;
Anguillesi, I. ;
Coltelli, M. B. ;
Fiori, S. ;
Montorsi, M. ;
Lazzeri, A. .
EXPRESS POLYMER LETTERS, 2016, 10 (04) :274-288
[7]   Thermo-oxidative degradation of isotactic polypropylene at high temperatures: phenolic antioxidants versus HAS [J].
Gensler, R ;
Plummer, CJG ;
Kausch, HH ;
Kramer, E ;
Pauquet, JR ;
Zweifel, H .
POLYMER DEGRADATION AND STABILITY, 2000, 67 (02) :195-208
[8]   Plastics of the Future? The Impact of Biodegradable Polymers on the Environment and on Society [J].
Haider, Tobias P. ;
Voelker, Carolin ;
Kramm, Johanna ;
Landfester, Katharina ;
Wurm, Frederik R. .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2019, 58 (01) :50-62
[9]   Proanthocyanidin glycosides and related polyphenols from cacao liquor and their antioxidant effects [J].
Hatano, T ;
Miyatake, H ;
Natsume, M ;
Osakabe, N ;
Takizawa, T ;
Ito, H ;
Yoshida, T .
PHYTOCHEMISTRY, 2002, 59 (07) :749-758
[10]   To compost or not to compost: Carbon and energy footprints of biodegradable materials' waste treatment [J].
Hermann, B. G. ;
Debeer, L. ;
De Wilde, B. ;
Blok, K. ;
Patel, M. K. .
POLYMER DEGRADATION AND STABILITY, 2011, 96 (06) :1159-1171