Phase separation in dilute solutions of poly (N-isopropylacrylamide)

被引：89
|
作者：
Gorelov, AV [1 ]
DuChesne, A [1 ]
Dawson, KA [1 ]
机构：
[1] NATL UNIV IRELAND UNIV COLL DUBLIN,DEPT CHEM,CTR COLLOID SCI & BIOMAT,DUBLIN 4,IRELAND
来源：
PHYSICA A | 1997年 / 240卷 / 3-4期
关键词：
polymer solution; aggregate; collapse; phase coexistence;
D O I：
10.1016/S0378-4371(97)00192-1
中图分类号：
O4 [物理学];
学科分类号：
0702 ;
摘要：
The appearance of spherical particles resulting from phase separation in dilute solutions of poly(N-isopropylacrylamide) has been observed by dynamic light scattering (DLS). The particles have a relatively narrow size distribution. The size of particles increases with increasing concentration of polymer, and decreasing heating speed. Electron microscopy confirms the existence of spherical particles with size and polydispersity in agreement with DLS.
引用
收藏
页码：443 / 452
页数：10
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