Tricyanomethane and its Salts with Nitrogen Bases: A Correction of Sixteen Reports

被引：8

作者：

Banert, Klaus ^{[1
]}

Hagedorn, Manfred ^{[1
]}

机构：

[1] Tech Univ Chemnitz, Organ Chem, Str Nationen 62, D-09111 Chemnitz, Germany

来源：

SYNLETT | 2019年 / 30卷 / 12期

关键词：

exclusion of structures; spectroscopic characterization; tricyanomethane; tricyanomethanide salts; unstable compounds; NANOSTRUCTURED MOLTEN-SALT; 1-METHYLIMIDAZOLIUM TRICYANOMETHANIDE; CATALYTIC APPLICATION; CYANOFORM; EXISTENCE; ACID;

D O I：

10.1055/s-0037-1611846

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A series of 16 articles, dealing with formation of tricyanomethanide salts from nitrogen bases (amines) and tricyanomethane, turned out to be wrong because no tricyanomethane or similar compounds are used and no tricyanomethanide salts are prepared. This statement is based mainly on the recently published spectroscopic data and depicted spectra, which are completely incompatible with the claimed structures. Some of the tricyanomethanide salts are now synthesized from nitrogen heterocycles and tricyanomethane or other precursors. The corresponding products show plausible spectroscopic data and physical properties, which are entirely different to those previously reported.

引用

页码：1427 / 1430

页数：4

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