Selective oxidation of alcohols with potassium permanganate adsorbed on silica gel under solvent-free conditions

被引：3
|
作者：
Lou, Ji-Dong [1 ]
Pan, Li-Li
Li, Li
Li, Feng
Gao, Chun-Ling
机构：
[1] China Inst Metrol, Coll Life Sci, Hangzhou 310018, Peoples R China
[2] Zhejiang Univ Technol, Coll Biol & Environm Engn, Hangzhou, Peoples R China
[3] Univ Nova Lisboa, Inst Tecnol Quim & Biol, P-2780 Oeiras, Portugal
[4] Uniformed Serv Univ Hlth Sci, Ctr Prostate Dis Res, Bethesda, MD 20814 USA
来源：
SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY | 2006年 / 36卷 / 10期
关键词：
alcohols; oxidation; aldehydes; ketones; potassium permanganate; silica gel;
D O I：
10.1080/15533170601028215
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new procedure for the selective oxidation of alcohols to the corresponding aldehydes and ketones with potassium permanganate supported on silica gel reagent at room temperature under solvent free conditions by shaking is reported. The present oxidations are completed within 60 min with the yield between 93-98%. Comparing with our more recent work, it is clearly shown that the reaction conditions of the present procedure are much milder.
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页码：729 / 731
页数：3
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