In situ Alkylation of 4,4′-Vinylenedipyridine for Inorganic-Organic Iodides/Iodidomercurates

被引：5

作者：

Cui, Jian-Qiu ^{[1
]}

Guo, Tian-Shuo ^{[1
]}

Chu, Kai-Bin ^{[1
]}

Wu, Chao ^{[1
]}

Yang, Gang ^{[1
]}

Song, Jun-Ling ^{[1
]}

Zhang, Chi ^{[1
]}

机构：

[1] Jiangnan Univ, Sch Chem & Mat Engn, China Australia Joint Res Ctr Funct Mol Mat, Wuxi 214122, Peoples R China

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2017年 / 643卷 / 07期

基金：

中国国家自然科学基金;

关键词：

Crystal structure; Mercury; Hybrid materials; In situ alkylation reactions; 4,4 '-Vinylenedipyridine; MERCURY(II) COORDINATION POLYMERS; CRYSTAL-STRUCTURES; HYDROTHERMAL SYNTHESIS; OPTICAL-PROPERTIES; COUNTER-ION; HYBRID; VIOLOGEN; PEROVSKITE; LIGANDS; COMPLEX;

D O I：

10.1002/zaac.201600431

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Solvothermal reactions of HgI2, 4,4'-vinylenedipyridine, and HI in alcoholic solution (methanol, ethanol, or pentanol) gave rise to a family of organic-inorganic hybrid complexes, formulated as [C14H16N2][I-4](2-) (1), [C16H20N2][HgI4] (2), and [C22H32N2][HgI4](4) (3). Single-crystal X-ray diffraction reveals that all three compounds are discrete structures, including the inorganic anion [I-4](2-) or [HgI4](2-) and an organic cation, where the resulting organic cations were generated in situ alkylation reactions of 4,4'-vinylenedipyridine with alcohols, with cleavage of the alcoholic C-O bond followed by a one-step in situ N-alkylation reaction of 4,4'-vinylenedipyridine in acidic HI solution. X-ray powder diffraction (XRD), H-1 NMR and C-13 NMR, energy-dispersive X-ray (EDS), IR, as well as UV/Vis/NIR spectroscopy, elemental analysis, and thermogravimetric analysis (TGA) were used to characterize the complexes.

引用

页码：483 / 487

页数：5

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