Metal-organic frameworks for photocatalysis

被引:309
作者
Li, Ying [1 ,2 ]
Xu, Hua [1 ,2 ]
Ouyang, Shuxin [1 ,2 ]
Ye, Jinhua [1 ,2 ,3 ]
机构
[1] Tianjin Univ, Tianjin Key Lab Composite & Funct Mat, Key Lab Adv Ceram & Machining Technol, TU NIMS Joint Res Ctr,Minist Educ,Sch Mat Sci & E, 92 Weijin Rd, Tianjin 300072, Peoples R China
[2] Collaborat Innovat Ctr Chem Sci & Engn Tianjin, Tianjin 300072, Peoples R China
[3] Natl Inst Mat Sci, Int Ctr Mat Nanoarchitecton WPI MANA, Environm Remediat Mat Unit, 1-1 Namiki, Tsukuba, Ibaraki 3050044, Japan
基金
中国国家自然科学基金;
关键词
PHOTOINDUCED CHARGE-TRANSFER; HYBRID POROUS SOLIDS; VISIBLE-LIGHT; HYDROGEN-PRODUCTION; CO2; REDUCTION; SEMICONDUCTOR; EFFICIENT; WATER; TIO2; ADSORPTION;
D O I
10.1039/c5cp05885f
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Photocatalysis is a promising technology to convert solar energy into chemical energy. Recently, metal-organic frameworks (MOFs) have emerged as novel photocatalysts owing to their inherent structural characteristics of a large surface area and a well-ordered porous structure. Most importantly, via modulation of the organic linker/metal clusters or incorporation with metal/complex catalysts, not only the reactant adsorption and light absorption but also the charge separation and reactant activation will be largely promoted, leading to superior photocatalytic performance. In this article, we will first introduce the photophysical/chemical properties of MOFs; then various strategies of modification of MOFs towards better photocatalytic activity will be presented; finally, we will address the challenge and further perspective in MOF-based photocatalysis.
引用
收藏
页码:7563 / 7572
页数:10
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