Molecular 2:1 digital multiplexer

被引:119
作者
Andreasson, Joakim [1 ]
Straight, Stephen D.
Bandyopadhyay, Subhajit
Mitchell, Reginald H.
Moore, Thomas A.
Moore, Ana L.
Gust, Devens
机构
[1] Chalmers, Dept Chem & Biol Engn, S-41296 Gothenburg, Sweden
[2] Arizona State Univ, Dept Chem & Biochem, Ctr Study Early Events Photosynth, Tempe, AZ 85287 USA
[3] Univ Victoria, Dept Chem, Victoria, BC V8W 3V6, Canada
关键词
chromophores; molecular devices; photochemistry; photochromism; porphyrinoids;
D O I
10.1002/anie.200603856
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
(Chemical Equation Presented) Two into one: A porphyrin linked to two photochromic moieties performs as a 2:1 digital multiplexer (MUX). It takes heat and red light as the two inputs (in 1 and in 2), and a third switchable input (green light, sel) selects whether the output (porphyrin fluorescence) reports the state of in 1 or in 2. Each photochromic moiety may be independently photoisomerized to isomers that quench the porphyrin fluorescence. © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码:958 / 961
页数:4
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