Molecular 2:1 digital multiplexer

被引:119
作者
Andreasson, Joakim [1 ]
Straight, Stephen D.
Bandyopadhyay, Subhajit
Mitchell, Reginald H.
Moore, Thomas A.
Moore, Ana L.
Gust, Devens
机构
[1] Chalmers, Dept Chem & Biol Engn, S-41296 Gothenburg, Sweden
[2] Arizona State Univ, Dept Chem & Biochem, Ctr Study Early Events Photosynth, Tempe, AZ 85287 USA
[3] Univ Victoria, Dept Chem, Victoria, BC V8W 3V6, Canada
关键词
chromophores; molecular devices; photochemistry; photochromism; porphyrinoids;
D O I
10.1002/anie.200603856
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
(Chemical Equation Presented) Two into one: A porphyrin linked to two photochromic moieties performs as a 2:1 digital multiplexer (MUX). It takes heat and red light as the two inputs (in 1 and in 2), and a third switchable input (green light, sel) selects whether the output (porphyrin fluorescence) reports the state of in 1 or in 2. Each photochromic moiety may be independently photoisomerized to isomers that quench the porphyrin fluorescence. © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码:958 / 961
页数:4
相关论文
共 23 条
[1]   Molecular AND logic gate based on electric dichroism of a photochromic dihydroindolizine [J].
Andréasson, J ;
Terazono, Y ;
Albinsson, B ;
Moore, TA ;
Moore, AL ;
Gust, D .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (46) :7591-7594
[2]   Molecule-based photonically switched half-adder [J].
Andréasson, J ;
Kodis, G ;
Terazono, Y ;
Liddell, PA ;
Bandyopadhyay, S ;
Mitchell, RH ;
Moore, TA ;
Moore, AL ;
Gust, D .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (49) :15926-15927
[3]  
Andreasson J, 2005, ANGEW CHEM, V117, P7763
[4]   All-photonic molecular half-adder [J].
Andreasson, Joakim ;
Straight, Stephen D. ;
Kodis, Gerdenis ;
Park, Choong-Do ;
Hambourger, Michael ;
Gervaldo, Miguel ;
Albinsson, Bo ;
Moore, Thomas A. ;
Moore, Ana L. ;
Gust, Devens .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (50) :16259-16265
[5]  
de Silva AP, 2002, CHEM-EUR J, V8, P4935, DOI 10.1002/1521-3765(20021104)8:21<4935::AID-CHEM4935>3.0.CO
[6]  
2-2
[7]   Digital photoswitching of fluorescence based on the photochromism of diarylethene derivatives at a single-molecule level [J].
Fukaminato, T ;
Sasaki, T ;
Kawai, T ;
Tamai, N ;
Irie, M .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (45) :14843-14849
[8]   Ni(II), Cu(II), and Zn(II) cryptate-enhanced fluorescence of a trianthrylcryptand: A potential molecular photonic OR operator [J].
Ghosh, P ;
Bharadwaj, PK ;
Mandal, S ;
Ghosh, S .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (06) :1553-1554
[9]   Lanthanide macrocyclic quinolyl conjugates as luminescent molecular-level devices [J].
Gunnlaugsson, T ;
Mac Dónaill, DA ;
Parker, D .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (51) :12866-12876
[10]   Monomolecular logic: "Half-adder" based on multistate/multifunctional photochromic spiropyrans [J].
Guo, XF ;
Zhang, DQ ;
Zhang, GX ;
Zhu, DB .
JOURNAL OF PHYSICAL CHEMISTRY B, 2004, 108 (32) :11942-11945