The semiclassical initial value series representation of the quantum propagator

被引:0
作者
Pollak, Eli [1 ]
机构
[1] Weizmann Inst Sci, Dept Chem Phys, IL-76100 Rehovot, Israel
来源
QUANTUM DYNAMICS OF COMPLEX MOLECULAR SYSTEMS | 2007年
关键词
D O I
暂无
中图分类号
O64 [物理化学(理论化学)、化学物理学]; O56 [分子物理学、原子物理学];
学科分类号
070203 ; 070304 ; 081704 ; 1406 ;
摘要
One of the central open challenges of the 21st century is the computation of real time quantum dynamics for systems with "many" degrees of freedom. A promising approach for obtaining approximate real time quantum dynamics is through the use of the semiclassical initial value approximation for the exact quantum propagator. The main drawback of this class of approximations was its ad hoc nature, it was in many senses an uncontrolled approximation scheme. This drawback has been recently remedied by showing that the semiclassical initial value representation (SCIVR) propagator is just a leading order term in a formally exact series representation of the true quantum propagator. In this review we present the SCIVR series representation, its successes and future challenges in applications to "large" systems. In addition, a new interaction representation initial value series representation for the exact quantum propagator is formulated.
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页码:259 / 271
页数:13
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