Structure and magnetism of new lanthanide 6-wheel compounds utilizing triethanolamine as a stabilizing ligand

被引：122
作者：
Langley, Stuart K. [1 ]
Moubaraki, Boujemaa [1 ]
Forsyth, Craig M. [1 ]
Gass, Ian A. [1 ]
Murray, Keith S. [1 ]
机构：
[1] Monash Univ, Sch Chem, Clayton, Vic 3800, Australia
来源：
DALTON TRANSACTIONS | 2010年 / 39卷 / 07期
关键词：
SINGLE-MOLECULE MAGNETS; ANISOTROPY; TETRANUCLEAR; DECANUCLEAR; MANGANESE; COMPLEX; IONS; DY;
D O I：
10.1039/b921843b
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The reaction of Ln(NO3)(3)center dot 6H(2)O (Ln = Gd, Dy) with triethanolamine (teaH(3)) and triethylamine in MeOH gives two isostructural hexanuclear wheels of formula [Ln(6)(teaH)(6)(NO3)(6)]center dot 8MeOH, the magnetic properties of which show slow magnetisation relaxation in the Dy case.
引用
收藏
页码：1705 / 1708
页数：4
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  • [11] Single molecule magnet with single lanthanide ion
    Ishikawa, Naoto
    [J]. POLYHEDRON, 2007, 26 (9-11) : 2147 - 2153
  • [12] Octalanthanide wheels supported by p-tert-butylsulfonylcalix[4]arene
    Kajiwara, T
    Wu, HS
    Ito, T
    Iki, N
    Miyano, S
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (14) : 1832 - 1835
  • [13] A dodecalanthanide wheel supported by p-tert-butylsulfonylcalix[4]aren
    Kajiwara, Takashi
    Katagiri, Kensuke
    Takaishi, Shinya
    Yamashita, Masahiro
    Iki, Nobuhiko
    [J]. CHEMISTRY-AN ASIAN JOURNAL, 2006, 1 (03) : 349 - 351
  • [14] A Dy10 Cluster Incorporates Two Sets of Vertex-Sharing Dy3 Triangles
    Ke, Hongshan
    Xu, Gong-Feng
    Zhao, Lang
    Tang, Jinkui
    Zhang, Xi-Yan
    Zhang, Hong-Jie
    [J]. CHEMISTRY-A EUROPEAN JOURNAL, 2009, 15 (40) : 10335 - 10338
  • [15] Structure and magnetism of decanuclear and octadecanuclear manganese(II/III) triethanolamine clusters
    Langley, Stuart K.
    Berry, Kevin J.
    Moubaraki, Boujemaa
    Murray, Keith S.
    [J]. DALTON TRANSACTIONS, 2009, (06) : 973 - 982
  • [16] Dinuclear Dysprosium(III) Single-Molecule Magnets with a Large Anisotropic Barrier
    Lin, Po-Heng
    Burchell, Tara J.
    Clerac, Rodolphe
    Murugesu, Muralee
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (46) : 8848 - 8851
  • [17] A Polynuclear Lanthanide Single-Molecule Magnet with a Record Anisotropic Barrier
    Lin, Po-Heng
    Burchell, Tara J.
    Ungur, Liviu
    Chibotaru, Liviu F.
    Wernsdorfer, Wolfgang
    Murugesu, Muralee
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (50) : 9489 - 9492
  • [18] PREPARATION, STRUCTURE, AND MAGNETIC-PROPERTIES OF A DODECANUCLEAR MIXED-VALENCE MANGANESE CARBOXYLATE
    LIS, T
    [J]. ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1980, 36 (SEP): : 2042 - 2046
  • [19] Heterometallic [Mn5-Ln4] single-molecule magnets with high anisotropy barriers
    Mereacre, Valeriu
    Ako, Ayuk M.
    Clerac, Rodolphe
    Wernsdorfer, Wolfgang
    Hewitt, Ian J.
    Anson, Christopher E.
    Powell, Annie K.
    [J]. CHEMISTRY-A EUROPEAN JOURNAL, 2008, 14 (12) : 3577 - 3584
  • [20] A bell-shaped Mn11Gd2 single-molecule magnet
    Mereacre, Valeriu M.
    Ako, Ayuk M.
    Clerac, Rodolphe
    Wernsdorfer, Wolfgang
    Filoti, George
    Bartolome, Juan
    Anson, Christopher E.
    Powell, Annie K.
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (30) : 9248 - +
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