Structure and magnetism of new lanthanide 6-wheel compounds utilizing triethanolamine as a stabilizing ligand

被引：125

作者：

Langley, Stuart K. ^{[1
]}

Moubaraki, Boujemaa ^{[1
]}

Forsyth, Craig M. ^{[1
]}

Gass, Ian A. ^{[1
]}

Murray, Keith S. ^{[1
]}

机构：

[1] Monash Univ, Sch Chem, Clayton, Vic 3800, Australia

来源：

DALTON TRANSACTIONS | 2010年 / 39卷 / 07期

关键词：

SINGLE-MOLECULE MAGNETS; ANISOTROPY; TETRANUCLEAR; DECANUCLEAR; MANGANESE; COMPLEX; IONS; DY;

D O I：

10.1039/b921843b

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of Ln(NO3)(3)center dot 6H(2)O (Ln = Gd, Dy) with triethanolamine (teaH(3)) and triethylamine in MeOH gives two isostructural hexanuclear wheels of formula [Ln(6)(teaH)(6)(NO3)(6)]center dot 8MeOH, the magnetic properties of which show slow magnetisation relaxation in the Dy case.

引用

页码：1705 / 1708

页数：4

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