Structure and magnetism of new lanthanide 6-wheel compounds utilizing triethanolamine as a stabilizing ligand

被引：122
作者：
Langley, Stuart K. [1 ]
Moubaraki, Boujemaa [1 ]
Forsyth, Craig M. [1 ]
Gass, Ian A. [1 ]
Murray, Keith S. [1 ]
机构：
[1] Monash Univ, Sch Chem, Clayton, Vic 3800, Australia
来源：
DALTON TRANSACTIONS | 2010年 / 39卷 / 07期
关键词：
SINGLE-MOLECULE MAGNETS; ANISOTROPY; TETRANUCLEAR; DECANUCLEAR; MANGANESE; COMPLEX; IONS; DY;
D O I：
10.1039/b921843b
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The reaction of Ln(NO3)(3)center dot 6H(2)O (Ln = Gd, Dy) with triethanolamine (teaH(3)) and triethylamine in MeOH gives two isostructural hexanuclear wheels of formula [Ln(6)(teaH)(6)(NO3)(6)]center dot 8MeOH, the magnetic properties of which show slow magnetisation relaxation in the Dy case.
引用
收藏
页码：1705 / 1708
页数：4
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