One-step solution synthesis of a two-dimensional semiconducting covalent organometallic nanosheet via the condensation of boronic acid

被引：2

作者：

Wang, Qijun ^{[1
]}

Yan, Jiahao ^{[2
]}

Xiao, Mingchao ^{[1
,3
]}

Manoj, Devaraj ^{[1
]}

Zhong, Cheng ^{[5
]}

Lv, Qiying ^{[1
]}

Yang, Lite ^{[1
]}

Wu, Liangmei ^{[2
]}

Wang, Zhuoping ^{[1
]}

Bao, Lihong ^{[2
]}

Gao, Hongjun ^{[2
]}

Xiao, Fei ^{[1
]}

Jiang, Lang ^{[3
]}

Wang, Shuai ^{[1
,4
]}

机构：

[1] Huazhong Univ Sci & Technol, Sch Chem & Chem Engn, Wuhan 430074, Hubei, Peoples R China

[2] Chinese Acad Sci, Inst Phys, Beijing 100190, Peoples R China

[3] Chinese Acad Sci, Inst Chem, Beijing 100190, Peoples R China

[4] Fudan Univ, Dept Mat Sci, Shanghai 200433, Peoples R China

[5] Wuhan Univ, Coll Chem & Mol Sci, Wuhan 430072, Hubei, Peoples R China

来源：

RSC ADVANCES | 2019年 / 9卷 / 50期

基金：

中国国家自然科学基金;

关键词：

ORGANIC FRAMEWORKS; CRYSTALLINE; POLYMER;

D O I：

10.1039/c9ra05806k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In this work, a 2D covalent organometallic nanosheet (COMS) was designed and successfully synthesized through the one-step conjunction of a terpyridine-metal-terpyridine (TMT) sandwich coordinate motif with borate ester covalent heterocyclic (B3O3) linkage via the condensation of boronic acid. The obtained 2D COMS with a cobalt coordination center (2D COMS-Co) showed promising p-type semiconducting properties.

引用

页码：29327 / 29330

页数：4

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