One-step solution synthesis of a two-dimensional semiconducting covalent organometallic nanosheet via the condensation of boronic acid

被引：2
|
作者：
Wang, Qijun [1 ]
Yan, Jiahao [2 ]
Xiao, Mingchao [1 ,3 ]
Manoj, Devaraj [1 ]
Zhong, Cheng [5 ]
Lv, Qiying [1 ]
Yang, Lite [1 ]
Wu, Liangmei [2 ]
Wang, Zhuoping [1 ]
Bao, Lihong [2 ]
Gao, Hongjun [2 ]
Xiao, Fei [1 ]
Jiang, Lang [3 ]
Wang, Shuai [1 ,4 ]
机构：
[1] Huazhong Univ Sci & Technol, Sch Chem & Chem Engn, Wuhan 430074, Hubei, Peoples R China
[2] Chinese Acad Sci, Inst Phys, Beijing 100190, Peoples R China
[3] Chinese Acad Sci, Inst Chem, Beijing 100190, Peoples R China
[4] Fudan Univ, Dept Mat Sci, Shanghai 200433, Peoples R China
[5] Wuhan Univ, Coll Chem & Mol Sci, Wuhan 430072, Hubei, Peoples R China
来源：
RSC ADVANCES | 2019年 / 9卷 / 50期
基金：
中国国家自然科学基金;
关键词：
ORGANIC FRAMEWORKS; CRYSTALLINE; POLYMER;
D O I：
10.1039/c9ra05806k
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
In this work, a 2D covalent organometallic nanosheet (COMS) was designed and successfully synthesized through the one-step conjunction of a terpyridine-metal-terpyridine (TMT) sandwich coordinate motif with borate ester covalent heterocyclic (B3O3) linkage via the condensation of boronic acid. The obtained 2D COMS with a cobalt coordination center (2D COMS-Co) showed promising p-type semiconducting properties.
引用
收藏
页码：29327 / 29330
页数：4
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