CONSTRUCTION OF ISOTHERMS IN SOLVENT EXTRACTION OF COPPER

被引:5
作者
Cvetkovski, Vladimir B. [1 ]
Conic, Vesna T. [1 ]
Vukovic, Milovan V. [2 ]
Stojanovski, Goran P. [3 ]
Cvetkovska, Milena V. [4 ]
机构
[1] Inst Min & Met, Bor, Serbia
[2] Univ Belgrade, Tech Fac, Bor, Serbia
[3] RBB, Bor, Serbia
[4] Univ Belgrade, Fac Chem, Belgrade, Serbia
关键词
Mine water; Equilibrium isotherms; Solvent extraction; Electrowining; Cathodic copper;
D O I
10.2298/HEMIND0904309C
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
The aim of this work is construction of equilibrium isotherms in solvent extraction. Technological parameters have been predicted for treatment of mine water by solvent extraction and electrowining. Two stages of extractions and one stage of stripping have been predicted for copper recovery by analyzing the equilibrium isotherms. The process was performed on mine water with 2,5 g/dm(3) Cu2+, 3 g/dm Fe2+, pH 1,8, using 9 vol% LIX 984N in kerosene (organic solvent), with 95 and 98% stages efficiencies, respectively. This course produced an advanced electrolyte solution, suitable for electrowining and cathodic copper recovery, containing 51 g/dm(3) Cu2+ and 160g/dm(3) H2SO4 from a 30 g/dm(3) Cu and 190 g/dm(3) H2SO4.
引用
收藏
页码:309 / 312
页数:4
相关论文
共 6 条
[1]  
CONIC V, 2008, PROIZVODNJA KATODNOG, P271
[2]  
HABASHI F, 1999, TXB HIDROMETALLURGY, P437
[3]  
Minango R, 2005, J S AFR I MIN METALL, V105, P593
[4]  
Sole KC, 2008, CAN METALL QUART, V47, P285, DOI 10.1179/000844308794408281
[5]   Selective separation of Cu(II), Zn(II), and Cd(II) by solvent extraction [J].
Xie Keng ;
Wen Hankang ;
Hua Yixin ;
Ruan Renman .
RARE METALS, 2008, 27 (03) :228-232
[6]   Performance and stability of supported liquid membranes using LIX 984N for copper transport [J].
Yang, XJ ;
Fane, AG .
JOURNAL OF MEMBRANE SCIENCE, 1999, 156 (02) :251-263