Research Progress in Multielectron Reactions in Polyanionic Materials for Sodium-Ion Batteries

被引：69
作者：
Liu, Rui [1 ]
Liang, Ziteng [1 ]
Gong, Zhengliang [2 ]
Yang, Yong [1 ,2 ]
机构：
[1] Xiamen Univ, Coll Chem & Chem Engn, Collaborat Innovat Ctr Chem Energy Mat, State Key Lab Phys Chem Solid Surface,Dept Chem, Xiamen 361005, Fujian, Peoples R China
[2] Xiamen Univ, Coll Energy, Xiamen 361005, Fujian, Peoples R China
来源：
SMALL METHODS | 2019年 / 3卷 / 04期
基金：
中国国家自然科学基金;
关键词：
multielectron reactions; polyanions; sodium-ion batteries; structural evolution; transition metals; POSITIVE ELECTRODE MATERIAL; HIGH-PERFORMANCE CATHODE; NA-ION; HIGH-VOLTAGE; ELECTROCHEMICAL PROPERTIES; HIGH-CAPACITY; PYROPHOSPHATE CATHODE; LITHIUM-INSERTION; LOW-COST; OXIDATIVE DEINTERCALATION;
D O I：
10.1002/smtd.201800221
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Realizing multielectron reactions in electrodes is crucial for improving the capacity and energy density of batteries. Polyanion-type compounds are suitable for exploring multielectron reactions due to their robust frameworks and structural diversity. This paper reviews the recent research progress on the study of multielectron reactions in Na-based polyanion compounds. The versatile polyanions are classified by transition metals (V, Mn, Fe, Ti, Cr, and Co). Both experimental efforts and theoretical calculations are analyzed and summarized, with a special focus on the reversibility, stability, and corresponding structural evolutions during the multielectron reactions. The challenges and opportunities of exploring polyanions with reversible and stable multielectron reactions are also discussed.
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页数：22
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