Conjugate reduction of α,β-unsaturated carbonyl compounds promoted by nickel nanoparticles

被引:35
作者
Alonso, Francisco
Osante, Inaki
Yus, Miguel
机构
[1] Univ Alicante, Dept Quim Organ, Fac Ciencias, E-03080 Alicante, Spain
[2] Univ Alicante, ISO, E-03080 Alicante, Spain
关键词
conjugate reduction; ketones; carboxylic acid derivatives; nickel; nanoparticles;
D O I
10.1055/s-2006-951494
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The system composed of nickel(II) chloride, lithium metal, a catalytic polymer-supported arene, and ethanol, has been efficiently applied to the conjugate reduction of a variety of a,p-unsaturated carbonyl compounds (ketones and carboxylic acid derivatives) under very mild reaction conditions.
引用
收藏
页码:3017 / 3020
页数:4
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